Decarboxylative Fluorination of Arylcarboxylic Acids Promoted by ortho-Hydroxy and Amino Groups

被引：23
|
作者：
Wang, Dinghai [1 ]
Yuan, Zheliang [1 ]
Liu, Qilun [1 ]
Chen, Pinhong [1 ]
Liu, Guosheng [1 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Univ Chinese Acad Sci, State Key Lab Organometall Chem,Ctr Excellence Mo, 345 Lingling Rd, Shanghai 200032, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2018年 / 36卷 / 06期
基金：
中国国家自然科学基金;
关键词：
metal-free; decarboxylative; fluorination; aryl carboxylic acids; COPPER-MEDIATED FLUORINATION; CATALYZED FLUORINATION; KINETIC CHARACTERISTICS; AROYLOXYL RADICALS; CARBOXYLIC-ACIDS; CHEMISTRY; PALLADIUM; AMINOFLUORINATION; EXPANSION; FLUORIDE;
D O I：
10.1002/cjoc.201800016
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel decarboxylative fluorination process has been developed for the synthesis of ortho-hydroxy/amino arylfluorides from salicylic acid analogs, in which the ortho-hydroxy/amino group plays an important role in the transformation. In addition, various arylfluorides are obtained in good to excellent yields under mild conditions.
引用
收藏
页码：507 / 514
页数：8
相关论文
共 39 条
1234