Nickel Nanoparticles Encapsulated in Few-Layer Nitrogen-Doped Graphene Derived from Metal-Organic Frameworks as Efficient Bifunctional Electrocatalysts for Overall

被引:636
作者
Xu, You [1 ,2 ]
Tu, Wenguang [1 ]
Zhang, Bowei [3 ]
Yin, Shengming [1 ]
Huang, Yizhong [3 ]
Kraft, Markus [4 ,5 ]
Xu, Rong [1 ,2 ,4 ]
机构
[1] Nanyang Technol Univ, Sch Chem & Biomed Engn, 62 Nanyang Dr, Singapore 637459, Singapore
[2] Natl Res Fdn, SinBeRISE CREATE, CREATE Tower,1 Create Way, Singapore 138602, Singapore
[3] Nanyang Technol Univ, Sch Mat Sci & Engn, 50 Nanyang Ave, Singapore 639798, Singapore
[4] Natl Res Fdn, CREATE C4T, CREATE Tower,1 Create Way, Singapore 138602, Singapore
[5] Univ Cambridge, Dept Chem Engn & Biotechnol, Cambridge CB2 3RA, England
基金
新加坡国家研究基金会;
关键词
HYDROGEN EVOLUTION REACTION; OXYGEN EVOLUTION; NANOSHEET ARRAYS; HIGH-PERFORMANCE; NANOWIRE ARRAYS; NI FOAM; WATER; CARBON; ALKALINE; OXIDE;
D O I
10.1002/adma.201605957
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nickel nanoparticles encapsulated in few-layer nitrogen-doped graphene (Ni@NC) are synthesized by using a Ni-based metal-organic framework as the precursor for high-temperature annealing treatment. The resulting Ni@NC materials exhibit highly efficient and ultrastable electrocatalytic activity toward the hydrogen evolution reaction and the oxygen evolution reaction as well as overall water splitting in alkaline environment.
引用
收藏
页数:9
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