Polymeric haloplumbates(II) templated by ethoxycarbonylmethyl viologen: Structure and enchanced thermochromism behavior

被引：8
作者：
Chen, Bao-Guo [1 ]
机构：
[1] Fuzhou Univ Int Studies & Trade, Res Ctr Sci Technol & Soc, Fuzhou 350202, Fujian, Peoples R China
来源：
INORGANIC AND NANO-METAL CHEMISTRY | 2017年 / 47卷 / 08期
关键词：
Polymeric haloplumbates; organic-inorganic hybrid; thermochromism; INORGANIC-ORGANIC HYBRIDS; REDUCED BAND-GAP; OPTICAL-PROPERTIES; PHASE-TRANSITION; PEROVSKITES; PHOTOCHROMISM; COMPLEXES; HYDROGEN; CATIONS; IODIDE;
D O I：
10.1080/24701556.2017.1284119
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new lead iodide/organic hybrid, {[(AeV)(PbI3)(2)](DMF)(2)}(n) (1) (AeV(2+) = N, N'- bis(ethoxycarbonylmethyl)-4,4'-bipyridinium) has been synthesized using solution method and structurally determined by X-ray diffraction method In 1, the (PbI3)(n-)(n) chain is constructed from face-sharing of PbI6 octahedra templated by a new viologen AeV(2+) C-HO and C-HI hydrogen bonds contribute to the structural extending from 1-D chain to 3-D network Its absorption spectrum was investigated, and the energy band gap of 207 eV indicates its potential semiconductor nature 1 displays an enchanced thermochromism behavior with a phase transition temperature of 70C
引用
收藏
页码：1220 / 1225
页数：6
相关论文
共 39 条
  • [1] Binuclear Bi(III) halide complexes with 4,4′-ethylenepyridinium cations: luminescence tuning by reversible solvation
    Adonin, Sergey A.
    Rakhmanova, Marianna E.
    Smolentsev, Anton I.
    Korolkov, Ilya V.
    Sokolov, Maxim N.
    Fedin, Vladimir P.
    [J]. NEW JOURNAL OF CHEMISTRY, 2015, 39 (07) : 5529 - 5533
  • [2] Thermochromic behavior and phase transition of new octanuclear polyiodobismuth(III)ate
    Adonin, Sergey A.
    Sokolov, Maxim N.
    Abramov, Pavel A.
    Kozlova, Svetlana G.
    Pishchur, Denis P.
    Sheludyakova, Lilya A.
    Fedin, Vladimir P.
    [J]. INORGANICA CHIMICA ACTA, 2014, 419 : 19 - 25
  • [3] Inorganic-organic hybrid materials: construction of the first polymeric channelled halometallate(II) system
    Aragoni, MC
    Arca, M
    Caltagirone, C
    Devillanova, FA
    Demartin, F
    Garau, A
    Isaia, F
    Lippolis, V
    [J]. CRYSTENGCOMM, 2005, 7 : 544 - 547
  • [4] On the optical properties of micro- and nanometric size PbI2 particles
    Baibarac, M
    Preda, N
    Mihut, L
    Baltog, I
    Lefrant, S
    Mevellec, JY
    [J]. JOURNAL OF PHYSICS-CONDENSED MATTER, 2004, 16 (13) : 2345 - 2356
  • [5] Synthesis and crystal structures of inorganic-organic hybrids incorporating an aromatic amine with a chiral functional group
    Billing, David G.
    Lemmerer, Andreas
    [J]. CRYSTENGCOMM, 2006, 8 (09): : 686 - 695
  • [6] BOND VALENCE AS AN AID TO UNDERSTANDING STEREOCHEMISTRY OF O AND F COMPLEXES OF SN(II), SB(III), TE(IV), I(V) AND XE(VI)
    BROWN, ID
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 1974, 11 (03) : 214 - 233
  • [7] An Inorganic Hole Conductor for Organo-Lead Halide Perovskite Solar Cells. Improved Hole Conductivity with Copper Iodide
    Christians, Jeffrey A.
    Fung, Raymond C. M.
    Kamat, Prashant V.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (02) : 758 - 764
  • [8] Corradi AB, 2001, INORG CHEM, V40, P218
  • [9] Structural characterization, vibrational, optical properties and DFT investigation of a new luminescent organic-inorganic material: (C6H14N)3Bi2I9
    Dammak, Hajer
    Yangui, Aymen
    Triki, Smail
    Abid, Younes
    Feki, Habib
    [J]. JOURNAL OF LUMINESCENCE, 2015, 161 : 214 - 220
  • [10] Frisch M. J., 2003, Gaussian, Inc
1234