First light-emitting neutral molecular rectangles

被引:116
作者
Rajendran, T
Manimaran, B
Lee, FY
Lee, GH
Peng, SM
Wang, CM
Lu, KL [1 ]
机构
[1] Acad Sinica, Inst Chem, Taipei 115, Taiwan
[2] Natl Taiwan Univ, Dept Chem, Taipei 107, Taiwan
[3] Natl Taiwan Normal Univ, Dept Chem, Taipei 117, Taiwan
关键词
D O I
10.1021/ic9912474
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Synthesis of the first light-emitting neutral rhenium-based molecular rectangles has been accomplished. The rectangles possess large cavities having no counterions inside the channels, and above all they are luminescent at room temperature with considerable quantum yield and lifetimes in the range of nanoseconds.
引用
收藏
页码:2016 / +
页数:3
相关论文
共 25 条
[1]   Mononuclear and binuclear ruthenium(II) complexes containing 2,2′-bipyridine or 1,10-phenanthroline and pyrazole-3,5-bis(benzimidazole).: Synthesis, structure, isomerism, spectroscopy, and proton-coupled redox activity [J].
Baitalik, S ;
Flörke, U ;
Nag, K .
INORGANIC CHEMISTRY, 1999, 38 (14) :3296-3308
[2]   Thin-film molecular materials based on tetrametallic "squares":: Nanoscale porosity and size-selective guest transport characteristics [J].
Bélanger, S ;
Hupp, JT ;
Stern, CL ;
Slone, RV ;
Watson, DF ;
Carrell, TG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (03) :557-563
[3]   Synthesis and characterization of molecular rectangles based upon rhenium Thiolate dimers [J].
Benkstein, KD ;
Hupp, JT ;
Stern, CL .
INORGANIC CHEMISTRY, 1998, 37 (21) :5404-+
[4]   Molecular rectangles based on rhenium(I) coordination chemistry [J].
Benkstein, KD ;
Hupp, JT ;
Stern, CL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (49) :12982-12983
[5]   The rational design of high symmetry coordination clusters [J].
Caulder, DL ;
Raymond, KN .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (08) :1185-1200
[6]   SELF-ASSEMBLY OF SQUARE MULTIPORPHYRIN ARRAYS BY METAL-ION COORDINATION [J].
DRAIN, CM ;
LEHN, JM .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (19) :2313-2315
[7]   Self-assembly of porphyrin arrays via coordination to transition metal bisphosphine complexes and the unique spectral properties of the product metallacyclic ensembles [J].
Fan, J ;
Whiteford, JA ;
Olenyuk, B ;
Levin, MD ;
Stang, PJ ;
Fleischer, EB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (12) :2741-2752
[8]   Supramolecular self-assembly of macrocycles, catenanes, and cages through coordination of pyridine-based ligands to transition metals [J].
Fujita, M ;
Ogura, G .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1996, 69 (06) :1471-1482
[9]   MACROCYCLIC POLYNUCLEAR COMPLEXES [(EN)M(4,4'-BPY)]4(NO3)8 (M = PD OR PT) AS INORGANIC CYCLOPHANE - THEIR ABILITY FOR MOLECULAR RECOGNITION [J].
FUJITA, M ;
YAZAKI, J ;
OGURA, K .
TETRAHEDRON LETTERS, 1991, 32 (40) :5589-5592
[10]  
GIORDANO PJ, 1979, J AM CHEM SOC, V101, P2888, DOI 10.1021/ja00505a016