Spectroscopic identification and antioxidant activity of glucosylated carotenoid metabolites from Cydonia vulgaris fruits

被引:37
作者
Fiorentino, Antonio [1 ]
D'Abrosca, Brigida [1 ]
Pacifico, Severina [1 ]
Mastellone, Claudio [1 ]
Piscopo, Vincenzo [1 ]
Monaco, Pietro [1 ]
机构
[1] Seconda Univ Napoli, Dipartimento Sci Vita, Ctr Reg Competenza Prod Agroalimentari, Lab Integrato Qualita & Sicurezza Alimenti, I-81100 Caserta, Italy
关键词
Cydonia vulgaris; degraded carotenoids; NMR spectroscopy; antioxidant activity;
D O I
10.1021/jf062125e
中图分类号
S [农业科学];
学科分类号
09 ;
摘要
Carotenoid metabolites are common plant constituents with significant importance for the flavor and aroma of fruits. Three new carotenoid derivatives, (2E, 4E)-8-hydroxy-2,7-dimethyl-2,4-decadiene-1,10- dioic acid 1-O-beta-D-glucopyranosyl ester (1), (2Z, 4E)-8-beta-D-glucopyranosyloxy-2,7-dimethyl-2,4- decadiene-1,10-dioic acid ( 3), and 3,9-dihydroxymegastigmast-5-ene-3-O-[beta-D-glucopyranosyl-(1 -> 6)]-beta-D-glucopyranoside (5), as well as three known compounds, have been isolated from the ethanolic extract of peels of Cydonia vulgaris, the fruit of a shrub belonging to the same family as the apple. All the compounds were identified by spectroscopic techniques, especially 1D and 2D NMR. Antioxidant activities of all the isolated metabolites were assessed by measuring their ability to scavenge DPPH radical and superoxide radical (O2(.-)) and to induce the reduction of Mo(VI).
引用
收藏
页码:9592 / 9597
页数:6
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