Study of Photoluminescence Excitation Spectra of Tris(8-hydroxyquinoline) aluminum(III) (Alq3) in Solutions and Films

被引:0
|
作者
Wang, Zhoulu [1 ]
Tsuboi, Taiju [1 ]
Liu, Xiang [1 ]
Huang, Wei [1 ]
机构
[1] Nanjing Tech Univ, Inst Adv Mat, Nanjing 211816, Jiangsu, Peoples R China
关键词
fluorescence spectroscopy; organic light-emitting diodes; penetration depth effect; photochemistry; UV/Vis spectroscopy;
D O I
10.1002/ijch.201400053
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Absorption, photoluminescence, and photoluminescence excitation (PLE) spectra have been investigated for tris(8-hydroxyquinoline) aluminum(III) (Alq(3)) in solution at various Alq(3) concentrations and in doped and neat films. The redshifted PLE spectra, with respect to the absorption spectra, are obtained, together with a dip located near the absorption band peak. The dip becomes deeper with increasing concentration. It is found that the unusual PLE spectra are caused by the penetration depth effect, not by previously suggested microcrystallites of Alq(3).
引用
收藏
页码:927 / 930
页数:4
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