Structure, sintering behavior and dielectric properties of silica-coated BaTiO3

被引:25
作者
Chen, RZ [1 ]
Cui, AL
Wang, HH
Gui, ZL
Li, LT
机构
[1] Tsing Hua Univ, Dept Mat Sci & Engn, Beijing 100084, Peoples R China
[2] Tsing Hua Univ, Dept Chem, Beijing 100084, Peoples R China
关键词
coating; SiO2; BaTiO3; sintering; dielectric;
D O I
10.1016/S0167-577X(01)00584-5
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Silica was homogeneously coated on the surface of barium titanate (BaTiO3, BT) fine particles via sol-gel method. The thickness of silica film was about 5 tun. High-resolution transmission electron microscope (HRTEM) investigation and energy dispersion spectrometry (EDS) analysis proved that there was silica coated on BaTiO3. The coating mechanism is that after BaTiO3 hydrolyzed slightly, Na2SiO3 gelatinized on the surface of TiO2. Compared with pure BaTiO3 the coating process can improve sintering behavior and flatten temperature coefficients (TC) curves of ceramics based on BaTiO3. (C) 2002 Elsevier Science B.V All rights reserved.
引用
收藏
页码:314 / 317
页数:4
相关论文
共 10 条
[1]  
Cui AL, 1998, CHEM J CHINESE U, V19, P1727
[2]   THE PREPARATION OF ULTRAFINE CERIA-STABILIZED ZIRCONIA PARTICLES COATED WITH YTTRIA [J].
DJURICIC, B ;
MCGARRY, D ;
PICKERING, S .
JOURNAL OF MATERIALS SCIENCE LETTERS, 1993, 12 (16) :1320-1323
[3]   COATING OF YTTRIA PRECURSOR ON ALN POWDER BY IN-SITU PRECIPITATION [J].
KIM, WJ ;
MOON, YT ;
KIM, CH ;
KIM, DK ;
LEE, HW .
JOURNAL OF MATERIALS SCIENCE LETTERS, 1994, 13 (18) :1349-1351
[4]  
Pearce D. H., 1993, 3 EUROCERAMICS, V1, P231
[5]   SOL-GEL COATING OF POWDERS FOR PROCESSING ELECTRONIC CERAMICS [J].
SELMI, FA ;
AMARAKOON, VRW .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1988, 71 (11) :934-937
[6]   SILICA COATING ON BARIUM-TITANATE PARTICLES [J].
SHIH, WH ;
KISAILUS, D ;
WEI, Y .
MATERIALS LETTERS, 1995, 24 (1-3) :13-15
[7]   The influence of different additives and the mode of their addition on the sintering behavior and the properties of semiconducting barium titanate ceramics [J].
Völtzke, D ;
Abicht, HP .
SOLID STATE SCIENCES, 2000, 2 (01) :149-159
[8]  
VOLZKE D, 1999, MATER CHEM PHYS, V61, P110
[9]   Microstructural homogeneity improvement in Si3N4 by a powder coating method [J].
Wang, CM .
JOURNAL OF MATERIALS SCIENCE, 1996, 31 (17) :4709-4718
[10]  
Wang SF, 1999, J AM CERAM SOC, V82, P2677, DOI 10.1111/j.1151-2916.1999.tb02141.x