Reaction of bis[bis(trimethylsilyl)methyl]germylene with tris(4-tert-butylphenyl)methylium ion:: Formation of a unique germyl cation weakly σ-coordinated to aromatic group

被引：9

作者：

Ichinohe, M ^{[1
]}

Hayata, Y ^{[1
]}

Sekiguchi, A ^{[1
]}

机构：

[1] Univ Tsukuba, Dept Chem, Tsukuba, Ibaraki 3058571, Japan

来源：

CHEMISTRY LETTERS | 2002年 / 10期

关键词：

D O I：

10.1246/cl.2002.1054

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of bis[bis(trimethylsilyl)methyl]germylene with tris(4-tert-butylphenyl)methylium TPFPB- in toluene produced an unexpected germyl cation, {[(Me3Si)(2)CH]Me(2)Si1}{[(4-tert-BuC6H4)(3)C]Me2Si}- HCMe2Ge+, which was formed through several consecutive rearrangements of the methyl, bis(trimethylsilyl)methyl, and triarylmethyl groups.

引用

页码：1054 / 1055

页数：2

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