Macromolecular helicity control of poly(phenyl isocyanate)s with a single stimuli-responsive chiral switch

被引：25

作者：

Fukuda, Mayu ^{[1
]}

Rodriguez, Rafael ^{[2
]}

Fernandez, Zulema ^{[3
,4
]}

Nishimura, Tatsuya ^{[1
]}

Hirose, Daisuke ^{[1
,2
]}

Watanabe, Go ^{[5
]}

Quinoa, Emilio ^{[3
,4
]}

Freire, Felix ^{[3
,4
]}

Maeda, Katsuhiro ^{[1
,2
]}

机构：

[1] Kanazawa Univ, Grad Sch Nat Sci & Technol, Kakuma Machi, Kanazawa, Ishikawa 9201192, Japan

[2] Kanazawa Univ, WPI Nano Life Sci Inst WPI NanoLSI, Kakuma Machi, Kanazawa, Ishikawa 9201192, Japan

[3] Univ Santiago de Compostela, Ctr Singular Invest Quim Biol & Mat Mol CiQUS, Santiago De Compostela 15782, Spain

[4] Univ Santiago de Compostela, Dept Quim Organ, Santiago De Compostela 15782, Spain

[5] Kitasato Univ, Sch Sci, Minami Ku, 1-15-1 Kitasato, Sagamihara, Kanagawa 2520373, Japan

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 55期

关键词：

CATION-PI INTERACTIONS; ASYMMETRIC POLYMERIZATION; SENSE; AMPLIFICATION; BEARING; MEMORY; POLYACETYLENE; SERGEANTS; PENDANTS; BRUSHES;

D O I：

10.1039/c9cc03555a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The introduction of a single chiral substituent with a switchable conformer equilibrium at the poly(phenyl isocyanate) terminus allowed the control of the helical sense of the polymer backbone using various external stimuli. Helical sense enhancement was achieved through a domino effect, where the helical sense was assigned by VCD spectroscopy and DFT calculations.

引用

页码：7906 / 7909

页数：4

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