Copper-Catalyzed Radical Reductive Arylation of Styrenes with Aryl Iodides Mediated by Zinc in Water

被引：20

作者：

Zhou, Feng ^{[1
,2
]}

Hu, Xiaoyun ^{[1
,2
,3
]}

Zhang, Wanying ^{[1
,2
]}

Li, Chao-Jun ^{[1
,2
]}

机构：

[1] McGill Univ, Dept Chem, 801 Sherbrooke St West, Montreal, PQ H3A 0B8, Canada

[2] McGill Univ, FQRNT Ctr Green Chem & Catalysis, 801 Sherbrooke St West, Montreal, PQ H3A 0B8, Canada

[3] South Cent Univ Nationalities, Coll Chem & Mat Sci, Wuhan 430074, Hubei, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 83卷 / 14期

基金：

加拿大自然科学与工程研究理事会;

关键词：

ORGANIC-REACTIONS; AQUEOUS-MEDIA; COUPLING REACTIONS; CROSS-COUPLINGS; C-C; ALKYL; CYCLIZATION; OLEFINS; HALIDES; FOCUS;

D O I：

10.1021/acs.joc.8b00278

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A copper/aniline catalyst system enables the radical arylation of styrenes using aryl iodides mediated by zinc in water. This transformation provides an efficient synthetic methodology for the convenient synthesis of diarylethane.

引用

页码：7416 / 7422

页数：7

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