Determination of the elastic properties of amorphous materials: Case study of alkali-silica reaction gel

被引:24
作者
Moon, Juhyuk [1 ]
Speziale, Sergio [2 ]
Meral, Cagla [3 ,4 ]
Kalkan, Bora [5 ]
Clark, Simon M. [5 ,6 ]
Monteiro, Paulo J. M. [3 ]
机构
[1] SUNY Stony Brook, Dept Mech Engn, Civil Engn Program, Stony Brook, NY 11794 USA
[2] Deutsch GeoForschungsZentrum GFZ, D-14473 Potsdam, Germany
[3] Univ Calif Berkeley, Dept Civil & Environm Engn, Berkeley, CA 94720 USA
[4] Middle E Tech Univ, Dept Civil Engn, TR-06800 Ankara, Turkey
[5] Lawrence Berkeley Lab, Adv Light Source, Berkeley, CA USA
[6] Macquarie Univ, Dept Earth & Planetary Sci, N Ryde, NSW 2109, Australia
关键词
Amorphous material; X-ray diffraction; Alkali-aggregate reaction; Elastic moduli; HIGH-PRESSURE; SINGLE-CRYSTAL; ASR GEL; TOBERMORITE; SCATTERING; CONSTANTS; ALUMINATE; KINETICS; DENSITY; STRESS;
D O I
10.1016/j.cemconres.2013.08.012
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
The gel formed during alkali-silica reaction (ASR) can lead to cracking and deterioration of a concrete structure. The elastic properties of the ASR gel using X-ray absorption and Brillouin spectroscopy measurements are reported. X-ray absorption was used to determine the density of the gel as a function of pressure, and the result yields an isothermal bulk modulus of 33 +/- 2 GPa. Brillouin spectroscopy was applied to measure isentropic bulk (24.9-34.0 GPa) and shear moduli (8.7-10.1 GPa) of the gel. The range of values obtained is attributed to the variable composition of samples that were collected under field conditions. Results suggested that amorphous silica becomes expanded and compressible as it absorbs water molecules and alkali ions. This could explain high gel migration rates through the complex pore structures in concrete. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:55 / 60
页数:6
相关论文
共 41 条
[1]  
ADAMS DM, 2000, J PHYS D, V15, P1609
[2]   The structure of alkali silicate gel by total scattering methods [J].
Benmore, C. J. ;
Monteiro, Paulo J. M. .
CEMENT AND CONCRETE RESEARCH, 2010, 40 (06) :892-897
[3]  
Berger M., NIST, PML, DOI [10.18434/T48G6X, DOI 10.18434/T48G6X]
[4]   FINITE STRAIN ISOTHERM AND VELOCITIES FOR SINGLE-CRYSTAL AND POLYCRYSTALLINE NACL AT HIGH-PRESSURES AND 300-DEGREE-K [J].
BIRCH, F .
JOURNAL OF GEOPHYSICAL RESEARCH, 1978, 83 (NB3) :1257-1268
[5]   Alkali activation of reactive silicas in cements: In situ Si-29 MAS NMR studies of the kinetics of silicate polymerization [J].
Brough, AR ;
Dobson, CM ;
Richardson, IG ;
Groves, GW .
JOURNAL OF MATERIALS SCIENCE, 1996, 31 (13) :3365-3373
[6]   Effect of pressure on the crystal structure of ettringite [J].
Clark, S. M. ;
Colas, B. ;
Kunz, M. ;
Speziale, S. ;
Monteiro, P. J. M. .
CEMENT AND CONCRETE RESEARCH, 2008, 38 (01) :19-26
[7]  
CUMMINS HZ, 1972, LASER HDB, P2
[8]  
Diamond S., 2000, proceeding of the 11th International conference on Alkali-aggregate Reaction in concrete, P31
[9]   Effects of aggregate size on alkali-silica-reaction induced expansion [J].
Dunant, Cyrille F. ;
Scrivener, Karen L. .
CEMENT AND CONCRETE RESEARCH, 2012, 42 (06) :745-751
[10]   Effects of uniaxial stress on alkali-silica reaction induced expansion of concrete [J].
Dunant, Cyrille F. ;
Scrivener, Karen L. .
CEMENT AND CONCRETE RESEARCH, 2012, 42 (03) :567-576