Synthesis of water-soluble fullerene and its isolation

被引：0

作者：

Akimoto, Y ^{[1
]}

Kudo, T ^{[1
]}

Shinoda, K ^{[1
]}

Jeyadevan, B ^{[1
]}

Tohji, K ^{[1
]}

Nirasawa, T ^{[1
]}

Kasuya, A ^{[1
]}

Nishina, Y ^{[1
]}

机构：

[1] Tohoku Univ, Dept Geosci & Technol, Sendai, Miyagi 9808579, Japan

来源：

PROCEEDINGS OF THE INTERNATIONAL SYMPOSIUM ON CLUSTER ASSEMBLED MATERIALS | 2001年 / 3卷

关键词：

water-soluble; fullerene oxide; dimeric fullerene oxide; alkali aqueous solution; HPLC;

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report a new and simple method to synthesize water-soluble fullerenes. Here, the fullerene oxides are simply boiled in alkali aqueous solution to obtain water-soluble species. The mass spectrometer of water-soluble sample confirmed the presence of C-60 suggesting the dissolution of the same in water. However, the fourier transform infrared (FT-IR) and ultraviolet-visible (UV-VIS) analysis suggested that the solution contains numerous species and their properties were different to that of C-60. To study the properties of water-soluble species in detail, the isolation using high performance liquid chromatography (HPLC) was attempted. The HPLC analysis of the products suggested the presence of several species of water-soluble fullerene derivatives and in most of the peaks, the presence of C-60 was confirmed. The results of the UV-VIS analysis confirmed the separation of soluble species by HPLC.

引用

页码：123 / 126

页数：4

共 50 条

[1] Recent Advances of Water-Soluble Fullerene Derivatives in Biomedical Applications
Zhang, Xiaoyan
Cong, Hailin
Yu, Bing
Chen, Qun
MINI-REVIEWS IN ORGANIC CHEMISTRY, 2019, 16 (01) : 92 - 99
[2] Facile Synthesis of Amino Acid Decorated Water-Soluble Fullerene Derivatives with Anti-influenza Activity
Bolshakova, Valeriya S.
Sinegubova, Ekaterina O.
Esaulkova, Yana L.
Peregudov, Alexander S.
Khakina, Ekaterina A.
Slesarenko, Nikita A.
Shestakov, Alexander F.
Zarubaev, Vladimir V.
Troshin, Pavel A.
Kraevaya, Olga A.
CHINESE JOURNAL OF CHEMISTRY, 2023, 41 (15): : 1803 - 1808
[3] SYNTHESIS OF NEW WATER-SOLUBLE CHOLESTEROL DERIVATIVES
Schmidt, Florian
Spoerner, Michael
Kalbitzer, Hans Robert
Koenig, Burkhard
SYNTHETIC COMMUNICATIONS, 2011, 41 (19) : 2876 - 2887
[4] Optimisation of the synthesis of a water-soluble sulfur black dye
Wang, M
Yang, JZ
Wang, HT
DYES AND PIGMENTS, 2001, 50 (03) : 243 - 246
[5] Sonoelectrochemical synthesis of water-soluble CdTe quantum dots
Shi, Jian-Jun
Wang, Sheng
He, Ting-Ting
Abdel-Halim, E. S.
Zhu, Jun-Jie
ULTRASONICS SONOCHEMISTRY, 2014, 21 (02) : 493 - 498
[6] Efficient Synthesis of Anionic and Cationic Water-Soluble Porphyrins
Chang, Yi
Liu, Mengyang
Niu, Mengyuan
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2017, 37 (09) : 2442 - 2448
[7] Synthesis and Characterization of the Water-Soluble Oleoyl Acetyl Chitosan
Ke, Weichang
Chen, Yikun
Peng, Xianghong
Zhu, Chao
Yang, Xiaoqiu
MATERIALS AND DESIGN, PTS 1-3, 2011, 284-286 : 1782 - +
[8] The Synthesis and Biological Applications of Water-Soluble Perylene Diimides
Wu, Jinjun
Yang, Zhen
Jiao, Jiannsei
Sun, Pengfei
Fan, Quli
Huang, Wei
PROGRESS IN CHEMISTRY, 2017, 29 (2-3) : 216 - 230
[9] Water-soluble Au(I) complexes, their synthesis and applications
Hristova, Yana R.
Kemper, Benedict
Besenius, Pol
TETRAHEDRON, 2013, 69 (49) : 10525 - 10533
[10] Stimuli-Responsive Water-Soluble Fullerene (C60) Polymeric Systems
Yao, Zhaoling
Tam, Kam Chiu
MACROMOLECULAR RAPID COMMUNICATIONS, 2011, 32 (23) : 1863 - 1885

← 1 2 3 4 5 →