An Efficient Method for Determination of the Diphenylamine (Stabilizer) in Propellants by Molecularly Imprinted Polymer based Carbon Paste Electrochemical Sensor

被引：35

作者：

Hande, Pankaj E. ^{[1
]}

Samui, Asit B. ^{[1
]}

Kulkarni, Prashant S. ^{[1
]}

机构：

[1] Def Inst Adv Tecnol, Dept Appl Chem, Pune, Maharashtra, India

来源：

PROPELLANTS EXPLOSIVES PYROTECHNICS | 2017年 / 42卷 / 04期

关键词：

Diphenylamine (DPA); Molecularly imprinted polymer; Propellant; Electrochemical sensor; Stabilizer; EXTRACTION;

D O I：

10.1002/prep.201600118

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

In this work we report efficient molecularly imprinted polymer (MIP) based carbon paste electrode sensor for the determination of diphenylamine in aged propellant. Initially, diphenylamine (DPA)-MIP was synthesized by using methacrylic acid (monomer) and ethylene glycol dimethyacrylate (cross-linker). Developed DPA-MIP was analyzed by Fourier transform infrared spectroscopy and Field-emission scanning electron microscopy. The sensor was incorporated as electrode in cyclic voltammetry. The sensor response was linear in the range of 0.5-3 mM DPA concentration. The lower detection limit obtained for sensor was 0.1 mM. The developed sensor was used for the determination of DPA in propellant systems. Same electrode was used for three repeated analysis without significant decrease in efficiency.

引用

页码：376 / 380

页数：5

共 16 条

[1] A new molecularly imprinted polymer (MIP)-based electrochemical sensor for monitoring 2,4,6-trinitrotoluene (TNT) in natural waters and soil samples [J].

Alizadeh, Taher ;

Zare, Mashaalah ;

Ganjali, Mohamad Reza ;

Norouzi, Parviz ;

Tavana, Babak .

BIOSENSORS & BIOELECTRONICS, 2010, 25 (05) :1166-1172

[2] VOLTAMMETRIC DETERMINATION OF THE STABILIZING ADDITIVES ACARDITE-II, CENTRALITE-I AND DIPHENYLAMINE IN PROPELLANTS [J].

BERGENS, A ;

LUNDSTROM, K ;

ASPLUND, J .

TALANTA, 1985, 32 (09) :893-899

[3] Electrochemical sensors based on molecularly imprinted polymers [J].

Blanco-López, MC ;

Lobo-Castañón, MJ ;

Miranda-Ordieres, AJ ;

Tuñón-Blanco, P .

TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2004, 23 (01) :36-48

[4] Recent advances in molecular imprinting technology: current status, challenges and highlighted applications [J].

Chen, Lingxin ;

Xu, Shoufang ;

Li, Jinhua .

CHEMICAL SOCIETY REVIEWS, 2011, 40 (05) :2922-2942

[5]

Curtis N. J., 1987, PROPELL EXPLOS PYROT, V163, P158

[6] Diphenylamine and derivatives in the environment: a review [J].

Drzyzga, O .

CHEMOSPHERE, 2003, 53 (08) :809-818

[7] Design of molecularly imprinted polymers for diphenylamine sensing [J].

Granado, V. L. V. ;

Rudnitskaya, A. ;

Oliveira, J. A. B. P. ;

Gomes, M. T. S. R. .

TALANTA, 2012, 94 :133-139

[8] Thin-film electrochemical sensor for diphenylamine detection using molecularly imprinted polymers [J].

Granado, Vera L. V. ;

Gutierrez-Capitan, Manuel ;

Fernandez-Sanchez, Cesar ;

Gomes, M. Teresa S. R. ;

Rudnitskaya, Alisa ;

Jimenez-Jorquera, Cecilia .

ANALYTICA CHIMICA ACTA, 2014, 809 :141-147

[9] A molecularly imprinted polymer with flash column chromatography for the selective and continuous extraction of diphenyl amine [J].

Hande, Pankaj E. ;

Samui, Asit B. ;

Kulkarni, Prashant S. .

RSC ADVANCES, 2015, 5 (90) :73434-73443

[10] Highly selective monitoring of metals by using ion-imprinted polymers [J].

Hande, Pankaj E. ;

Samui, Asit B. ;

Kulkarni, Prashant S. .

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2015, 22 (10) :7375-7404

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