Bicyclo[10.10.10]dotriacontanes:: the largest bicyclo[n.n.n]alkane ever known

被引：7

作者：

Kurata, H ^{[1
]}

Rikitake, N ^{[1
]}

Okumura, A ^{[1
]}

Oda, M ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Sci, Dept Chem, Toyonaka, Osaka 5600043, Japan

来源：

CHEMISTRY LETTERS | 2004年 / 33卷 / 08期

关键词：

D O I：

10.1246/cl.2004.1018

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bicyclo[10.10.10]dotriacontanes, the largest bicyclo[n.n.n]-alkanes ever known, have been first synthesized by Raney nickel reduction of trithienyltmethanophanes consisiting of two tris(2-thienyl)methanes and three etheno bridges. X-ray crystallographic analysis of a crystalline derivative confirmed the structure, though disorder of included hexane molecules lowered the accuracy.

引用

页码：1018 / 1019

页数：2

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