Corrosion resistance and antibacterial activity of electrosynthesized polypyrrole

被引：62

作者：

El Jaouhari, A. ^{[1
]}

El Asbahani, A. ^{[1
,3
]}

Bouabdallaoui, M. ^{[2
]}

Aouzal, Z. ^{[2
]}

Filotas, D. ^{[4
,5
]}

Bazzaoui, E. A. ^{[2
]}

Nagy, L. ^{[5
]}

Nagy, G. ^{[4
,5
]}

Bazzaoui, M. ^{[1
]}

Albourine, A. ^{[1
]}

Hartmann, D. ^{[3
]}

机构：

[1] Univ Ibn Zohr, Fac Sci, Dept Chim, Lab Mat & Environm,Equipe Chim Coordinat, BP 8106, Agadir, Morocco

[2] Univ Mohammed Ier, Fac Sci, Dept Chim, Oujda 60000, Morocco

[3] Univ Lyon 1, Fac Pharm, ISPB, Dept Pharmaceut Sante Publ,Lab Microbiol,Equipe I, Lyon, France

[4] Univ Pecs, Fac Sci, Dept Gen & Phys Chem, Ifjusag Utja 6, H-7624 Pecs, Hungary

[5] Univ Pecs, Janos Szentagothai Res Ctr, Ifjusag Utja 20, H-7624 Pecs, Hungary

来源：

SYNTHETIC METALS | 2017年 / 226卷

关键词：

Polypyrrole; Electrosynthesis; Corrosion; Antibacterial surfaces; MILD-STEEL; ELECTROCHEMICAL SYNTHESIS; ANODIC POLYMERIZATION; SILVER DEPOSITION; AQUEOUS-SOLUTION; PROTECTION; COATINGS; FILMS; IRON; BEHAVIOR;

D O I：

10.1016/j.synthmet.2017.01.008

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

In this work, we describe a method for coating a carbon steel surface by (PPy) layers to improve its corrosion resistance capabilities and also these antimicrobial properties. The coating was obtained by electrosynthesis in the sodium salicylate solution using cyclic voltammetry and galvanostatic techniques. Surface analysis by XPS, SEM and Raman spectroscopy confirmed the electrodeposition, stability and morphology of (PPy) film on the carbon steel surface. The corrosion protection properties of the coatings were examined by OCP, EIS and atomic adsorption spectroscopy revealing a high degree of corrosion resistance in salt containing medium. The antibacterial activity of the modified surface was assessed by using the standardized method ISO 22196 confirming enhancement of the antibacterial activity of this coated material comparing the untreated surface to the Silver/PPy coated carbon steel. This coated carbon steel material acquired interesting qualities of corrosion resistance, low cost and antibacterial for many industrial applications. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：15 / 24

页数：10

共 70 条

[1] A PHOTOELECTROCHEMICAL STUDY OF THE ANODIC-OXIDATION OF COPPER IN ALKALINE-SOLUTION [J].

ABRANTES, LM ;

CASTILLO, LM ;

NORMAN, C ;

PETER, LM .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 163 (1-2) :209-221

[2] A one-step electrosynthesis of PPy films on zinc substrates by anodic polymerization of pyrrole in aqueous solution [J].

Aeiyach, S ;

Zaid, B ;

Lacaze, PC .

ELECTROCHIMICA ACTA, 1999, 44 (17) :2889-2898

[3] Corrosion protection of copper using polypyrrole electrosynthesised from a salicylate solution [J].

Annibaldi, V. ;

Rooney, A. D. ;

Breslin, C. B. .

CORROSION SCIENCE, 2012, 59 :179-185

[4]

[Anonymous], WIREL SENSOR NETW, DOI DOI 10.1371/J0URNAL.PPAT.1000520

[5] Iron and Pseudomonas aeruginosa biofilm formation [J].

Banin, E ;

Vasil, ML ;

Greenberg, EP .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2005, 102 (31) :11076-11081

[6] Sweet aqueous solution for electrochemical synthesis of polypyrrole part 1B: On copper and its alloys [J].

Bazzaoui, A. ;

Martins, J. I. ;

Bazzaoui, E. A. ;

Martins, L. ;

Machnikova, E. .

ELECTROCHIMICA ACTA, 2007, 52 (11) :3568-3581

[7] Polypyrrole films electrosynthesized on stainless steel grid from saccharinate aqueous solution and its behaviour toward acetone vapor [J].

Bazzaoui, M. ;

Martins, J. I. ;

Machnikova, E. ;

Bazzaoui, E. A. ;

Martins, L. .

EUROPEAN POLYMER JOURNAL, 2007, 43 (04) :1347-1358

[8] Sweet aqueous solution for electrochemical synthesis of polypyrrole Part 2. On ferrous metals [J].

Bazzaoui, M. ;

Martins, J. I. ;

Costa, S. C. ;

Bazzaoui, E. A. ;

Reis, T. C. ;

Martins, L. .

ELECTROCHIMICA ACTA, 2006, 51 (21) :4516-4527

[9] Corrosion protection of stainless steel plates in fuel cells environment by conducting polymers [J].

Bazzaoui, M. ;

Martins, J. I. ;

Bazzaoui, E. A. ;

Albourine, A. ;

Martins, L. .

MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION, 2014, 65 (01) :67-75

[10] FILMFORMING ELECTROPOLYMERIZATION OF PYRROLE ON IRON IN AQUEOUS OXALIC-ACID [J].

BECK, F ;

MICHAELIS, R ;

SCHLOTEN, F ;

ZINGER, B .

ELECTROCHIMICA ACTA, 1994, 39 (02) :229-234

← 1 2 3 4 5 6 7 →