Disordered Cellulose-Based Nanostructures for Enhanced Light Scattering

被引:46
作者
Caixeiro, Soraya [1 ]
Peruzzo, Matilda [1 ,3 ]
Onelli, Olimpia D. [2 ]
Vignolini, Silvia [2 ]
Sapienza, Riccardo [1 ]
机构
[1] Kings Coll London, Dept Phys, London WC2R 2LS, England
[2] Univ Cambridge, Dept Chem, Lensfield Rd, Cambridge CB2 1EW, England
[3] Inst Sci & Technol Austria IST Austria, A-3400 Klosterneuburg, Austria
基金
英国生物技术与生命科学研究理事会; 欧洲研究理事会; 英国工程与自然科学研究理事会;
关键词
cellulose nanocystals; photonics; scattering; photonic glass; diffusion; disorder; NANOCRYSTALS; FILMS; NANOCOMPOSITES; TRANSPORT;
D O I
10.1021/acsami.6b15986
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Cellulose is the most abundant biopolymer on Earth. Cellulose fibers, such as the one extracted form cotton or woodpulp, have been used by humankind for hundreds of years to make textiles and paper. Here we show how, by engineering light matter interaction, we can optimize light scattering using exclusively cellulose nanocrystals. The produced material is sustainable, biocompatible, and when compared to ordinary microfiber-based paper, it shows enhanced scattering strength (X4), yielding a transport mean free path as low as 3.5 mu M in the visible light range. The experimental results are in a good agreement with the theoretical predictions obtained with a diffusive model for light propagation.
引用
收藏
页码:7885 / 7890
页数:6
相关论文
共 30 条
[1]   General procedure for determining cellulose nanocrystal sulfate half-ester content by conductometric titration [J].
Beck, Stephanie ;
Methot, Myriam ;
Bouchard, Jean .
CELLULOSE, 2015, 22 (01) :101-116
[2]  
Bohren C F., 1983, Absorption and Scattering of Light by Small Particles
[3]   Bright-White Beetle Scales Optimise Multiple Scattering of Light [J].
Burresi, Matteo ;
Cortese, Lorenzo ;
Pattelli, Lorenzo ;
Kolle, Mathias ;
Vukusic, Peter ;
Wiersma, Diederik S. ;
Steiner, Ullrich ;
Vignolini, Silvia .
SCIENTIFIC REPORTS, 2014, 4
[4]  
Caixeiro S., 2017, ACS APPL MATER INTER, DOI [10.1021/acsami.6b15986, 10.6084/m9.figshare.4598239, DOI 10.1021/ACSAMI.6B15986.SEE]
[5]   Silk-Based Biocompatible Random Lasing [J].
Caixeiro, Soraya ;
Gaio, Michele ;
Marelli, Benedetto ;
Omenetto, Fiorenzo G. ;
Sapienza, Riccardo .
ADVANCED OPTICAL MATERIALS, 2016, 4 (07) :998-1003
[6]   Electrogenerated Chemiluminescence Detection in Paper-Based Microfluidic Sensors [J].
Delaney, Jacqui L. ;
Hogan, Conor F. ;
Tian, Junfei ;
Shen, Wei .
ANALYTICAL CHEMISTRY, 2011, 83 (04) :1300-1306
[7]   Paper-supported 3D cell culture for tissue-based bioassays [J].
Derda, Ratmir ;
Laromaine, Anna ;
Mammoto, Akiko ;
Tang, Sindy K. Y. ;
Mammoto, Tadanori ;
Ingber, Donald E. ;
Whitesides, George M. .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2009, 106 (44) :18457-18462
[8]   INFLUENCE OF BOUNDARY REFLECTION AND REFRACTION ON DIFFUSIVE PHOTON TRANSPORT [J].
DURIAN, DJ .
PHYSICAL REVIEW E, 1994, 50 (02) :857-866
[9]   Review: current international research into cellulose nanofibres and nanocomposites [J].
Eichhorn, S. J. ;
Dufresne, A. ;
Aranguren, M. ;
Marcovich, N. E. ;
Capadona, J. R. ;
Rowan, S. J. ;
Weder, C. ;
Thielemans, W. ;
Roman, M. ;
Renneckar, S. ;
Gindl, W. ;
Veigel, S. ;
Keckes, J. ;
Yano, H. ;
Abe, K. ;
Nogi, M. ;
Nakagaito, A. N. ;
Mangalam, A. ;
Simonsen, J. ;
Benight, A. S. ;
Bismarck, A. ;
Berglund, L. A. ;
Peijs, T. .
JOURNAL OF MATERIALS SCIENCE, 2010, 45 (01) :1-33
[10]   Mind the Microgap in Iridescent Cellulose Nanocrystal Films [J].
Fernandes, Susete N. ;
Almeida, Pedro L. ;
Monge, Nuno ;
Aguirre, Luis E. ;
Reis, Dennys ;
de Oliveira, Cristiano L. P. ;
Neto, Antonio M. F. ;
Pieranski, Pawel ;
Godinho, Maria H. .
ADVANCED MATERIALS, 2017, 29 (02)