Synthesis and Characterization of Nanostructure BPO4

被引：18

作者：

Chen, Shuang ^{[1
,2
]}

Ye, Ming ^{[2
,3
]}

Chen, Hao-Hong ^{[1
]}

Yang, Xin-Xin ^{[1
]}

Zhao, Jing-Tai ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing, Peoples R China

[3] Chinese Acad Sci, Shanghai Inst Appl Phys, Single Mol Detecting & Manipulating Lab, Shanghai 200050, Peoples R China

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2009年 / 19卷 / 02期

关键词：

Nano-sized BPO4; Core-shell BPO4; n-Alkylamine; Hydrothermal synthesis;

D O I：

10.1007/s10904-008-9245-5

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Boron phosphate (BPO4) is a well known catalyst for a range of organic chemical reactions. In this paper, we report the preparations and characterizations of nano-sized BPO4 and nano-BPO4-based core-shell spheres. The samples were synthesized hydrothermally using H3BO3, H3PO4 and short chain n-alkylamines (n = 3, 4) as starting materials. The resulting products were characterized by powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), scan electron microscopy (SEM) and transmission electron microscopy (TEM), respectively. A possible mechanism for the formation of the materials is also discussed.

引用

页码：139 / 142

页数：4

共 31 条

[1] The isotopic effect and spectroscopic studies of boron orthophosphate (BPO4) [J].

Adamczyk, A ;

Handke, M .

JOURNAL OF MOLECULAR STRUCTURE, 2000, 555 :159-164

[2]

Baykal A, 2001, TURK J CHEM, V25, P425

[3]

Caruso F, 2001, ADV MATER, V13, P11, DOI 10.1002/1521-4095(200101)13:1<11::AID-ADMA11>3.0.CO

[4]

2-N

[5] Nanoengineering of inorganic and hybrid hollow spheres by colloidal templating [J].

Caruso, F ;

Caruso, RA ;

Möhwald, H .

SCIENCE, 1998, 282 (5391) :1111-1114

[6] Templated synthesis of mesolamellar n-alkylamine borophosphates [J].

Chen, Shuang ;

Borrmann, Horst ;

Huang, Ya-Xi ;

Zhang, Zhi-Jun ;

Chen, Hao-Hong ;

Zhao, Jing-Tai .

LANGMUIR, 2008, 24 (17) :9323-9327

[7] Nanostructure engineering by templated self-assembly of block copolymers [J].

Cheng, JY ;

Mayes, AM ;

Ross, CA .

NATURE MATERIALS, 2004, 3 (11) :823-828

[8] Microsize and nanosize BPO4 from pyrolysis of a carborane-substituted polyphosphazene [J].

Diaz, Carlos ;

Abizanda, Domingo ;

Jimenez, Josefina ;

Laguna, Antonio ;

Valenzuela, Maria Luisa .

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2006, 16 (03) :211-218

[9] The isomerization of 1-butene on stoichiometric and nonstoichiometric boron phosphate: The dependence of the acidity on stoichiometry [J].

Gao, S ;

Moffat, JB .

JOURNAL OF CATALYSIS, 1998, 180 (02) :142-148

[10] Novel Ti-base nanostructure-dendrite composite with enhanced plasticity [J].

He, G ;

Eckert, J ;

Löser, W ;

Schultz, L .

NATURE MATERIALS, 2003, 2 (01) :33-37

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