Polynuclear titanocene complexes with antimony ligands: [(Cp2Ti)2(SbR2)2] (R = Et), [(Cp2Ti)3(SbR)3Sb] [R=2-(Me2NCH2)C6H4] and [(Cp2Ti)5(SbR)2Sb7] (R = Me3SiCH2)

被引:10
作者
Breunig, Hans J. [1 ]
Lork, Enno [1 ]
Moldovan, Ovidiu [1 ]
Rat, Ciprian I. [2 ]
Rosenthal, Uwe [3 ]
Silvestru, Cristian [2 ]
机构
[1] Univ Bremen, Inst Anorgan & Phys Chem, D-28334 Bremen, Germany
[2] Univ Babes Bolyai, Fac Chim Ingn Chim, RO-400028 Cluj Napoca, Romania
[3] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany
关键词
ZINTL COMPOUNDS; BOND FORMATION; ELIMINATION; ZIRCONOCENE; ZIRCONIUM; SYSTEM;
D O I
10.1039/b904846d
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The formation and crystal structure of [(Cp2Ti)(2)(SbR2)(2)] (1, R = Et), [(Cp2Ti)(3)(SbR)(3)Sb] [2, R = 2-(Me2NCH2)C6H4], and [(Cp2Ti)(5)(SbR)(2)Sb-7] (3, R = Me3SiCH2) is reported.
引用
收藏
页码:5065 / 5067
页数:3
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