Polynuclear titanocene complexes with antimony ligands: [(Cp2Ti)2(SbR2)2] (R = Et), [(Cp2Ti)3(SbR)3Sb] [R=2-(Me2NCH2)C6H4] and [(Cp2Ti)5(SbR)2Sb7] (R = Me3SiCH2)

被引:10
作者
Breunig, Hans J. [1 ]
Lork, Enno [1 ]
Moldovan, Ovidiu [1 ]
Rat, Ciprian I. [2 ]
Rosenthal, Uwe [3 ]
Silvestru, Cristian [2 ]
机构
[1] Univ Bremen, Inst Anorgan & Phys Chem, D-28334 Bremen, Germany
[2] Univ Babes Bolyai, Fac Chim Ingn Chim, RO-400028 Cluj Napoca, Romania
[3] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany
关键词
ZINTL COMPOUNDS; BOND FORMATION; ELIMINATION; ZIRCONOCENE; ZIRCONIUM; SYSTEM;
D O I
10.1039/b904846d
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The formation and crystal structure of [(Cp2Ti)(2)(SbR2)(2)] (1, R = Et), [(Cp2Ti)(3)(SbR)(3)Sb] [2, R = 2-(Me2NCH2)C6H4], and [(Cp2Ti)(5)(SbR)(2)Sb-7] (3, R = Me3SiCH2) is reported.
引用
收藏
页码:5065 / 5067
页数:3
相关论文
共 25 条
[1]  
ANAGNOSTOPOULOS AK, 1966, CHIM CHRONIKA, V31, P141
[2]  
[Anonymous], THEOR CHEM
[3]   A synthetic and structural study of the formation of cyclic [(RP)nE]- anions and Zintl compounds using E(NMe2)3 (E = As, Sb) [J].
Bashall, A ;
Beswick, MA ;
Choi, N ;
Hopkins, AD ;
Kidd, SJ ;
Lawson, YG ;
Mosquera, MEG ;
McPartlin, M ;
Raithby, PR ;
Wheatley, AAEH ;
Wood, JA ;
Wright, DS .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (04) :479-486
[4]   Low-temperature synthesis of zintl compounds with a single-source molecular precursor [J].
Beswick, MA ;
Choi, N ;
Harmer, CN ;
Hopkins, AD ;
McPartlin, M ;
Wright, DS .
SCIENCE, 1998, 281 (5382) :1500-1501
[5]   Syntheses and structures of distibene complexes of tungsten and titanium:: [W(CO)5{(2,6-MeS2C6H3)2Sb2}] (Mes=2,4,6-Me3C6H2) and [CP2Ti{(2,6-MeS2C6H3)2Sb2)}] [J].
Breunig, Hans J. ;
Borrmann, Tobias ;
Lork, Enno ;
Rat, Ciprian I. ;
Rosenthal, Uwe .
ORGANOMETALLICS, 2007, 26 (22) :5364-5368
[6]   Syntheses of the antimonides R2Sb- (R = Ph, Mes, tBu, tBu2Sb) and Sb73- by reactions of organoantimony hydrides or cyclo-(tBuSb)4 with Li, Na, K, or BuLi [J].
Breunig, HJ ;
Ghesner, ME ;
Lork, E .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2005, 631 (05) :851-856
[7]  
COOL LB, 1985, ANGEW CHEM, V97, P425
[8]  
COOL LB, 1985, ANGEW CHEM INT EDIT, V24, P394
[9]   STRUCTURE AND MAGNETIC-PROPERTIES OF [CP2M(MU-PET2)]2 (M = TI, ZR) [J].
DICK, DG ;
STEPHAN, DW .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1991, 69 (07) :1146-1152
[10]   BIS(PI-CYCLOPENTADIENYL)(1,2,3-TRIPHENYLTRIPHOSPHANATO-P1,P3)-TITANIUM"AND ZIRCONIUM [J].
ISSLEIB, K ;
WILLE, G ;
KRECH, F .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1972, 11 (06) :527-&