High performance batteries based on hybrid magnesium and lithium chemistry

被引：164

作者：

Cheng, Yingwen ^{[1
]}

Shao, Yuyan ^{[1
]}

Ji-Guang Zhang ^{[1
]}

Sprenkle, Vincent L. ^{[1
]}

Liu, Jun ^{[1
]}

Li, Guosheng ^{[1
]}

机构：

[1] Pacific NW Natl Lab, Energy Proc & Mat Div, Richland, WA 99354 USA

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 68期

关键词：

RECHARGEABLE MG BATTERIES; ELECTROLYTE-SOLUTIONS; STORAGE;

D O I：

10.1039/c4cc03620d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This work studied hybrid batteries assembled with a Mg metal anode, a Li+ ion intercalation cathode and a dual-salt electrolyte containing Mg2+ and Li+ ions. We show that such hybrid batteries were able to combine the advantages of Li and Mg electrochemistry. They delivered outstanding rate performance (83% capacity retention at 15 C) with superior safety and stability (similar to 5% fade for 3000 cycles).

引用

页码：9644 / 9646

页数：3

共 20 条

[1] Prototype systems for rechargeable magnesium batteries [J].

Aurbach, D ;

Lu, Z ;

Schechter, A ;

Gofer, Y ;

Gizbar, H ;

Turgeman, R ;

Cohen, Y ;

Moshkovich, M ;

Levi, E .

NATURE, 2000, 407 (6805) :724-727

[2] Progress in rechargeable magnesium battery technology [J].

Aurbach, Doron ;

Suresh, Gurukar Shivappa ;

Levi, Elena ;

Mitelman, Ariel ;

Mizrahi, Oren ;

Chusid, Orit ;

Brunelli, Michela .

ADVANCED MATERIALS, 2007, 19 (23) :4260-+

[3] Effect of Electrolytic Properties of a Magnesium Organohaloaluminate Electrolyte on Magnesium Deposition [J].

Benmayza, Aadil ;

Ramanathan, Mayandi ;

Arthur, Timothy S. ;

Matsui, Masaki ;

Mizuno, Fuminori ;

Guo, Jinghua ;

Glans, Per-Anders ;

Prakash, Jai .

JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (51) :26881-26888

[4] Electrochemically stable cathode current collectors for rechargeable magnesium batteries [J].

Cheng, Yingwen ;

Liu, Tianbiao ;

Shao, Yuyan ;

Engelhard, Mark H. ;

Liu, Jun ;

Li, Guosheng .

JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (08) :2473-2477

[5] Novel, electrolyte solutions comprising fully inorganic salts with high anodic stability for rechargeable magnesium batteries [J].

Doe, Robert E. ;

Han, Ruoban ;

Hwang, Jaehee ;

Gmitter, Andrew J. ;

Shterenberg, Ivgeni ;

Yoo, Hyun Deog ;

Pour, Nir ;

Aurbach, Doron .

CHEMICAL COMMUNICATIONS, 2014, 50 (02) :243-245

[6] Electrical Energy Storage for the Grid: A Battery of Choices [J].

Dunn, Bruce ;

Kamath, Haresh ;

Tarascon, Jean-Marie .

SCIENCE, 2011, 334 (6058) :928-935

[7] Electrochemical and Spectroscopic Analysis of Mg2+ Intercalation into Thin Film Electrodes of Layered Oxides: V2O5 and MoO3 [J].

Gershinsky, Gregory ;

Yoo, Hyun Deog ;

Gofer, Yosef ;

Aurbach, Doron .

LANGMUIR, 2013, 29 (34) :10964-10972

[8]

Guohua L., 1995, J POWER SOURCES, V54, P519

[9] Molten salt synthesis (MSS) Of Cu2Mo6S8- : New way for large-scale production of Chevrel phases [J].

Lancry, E ;

Levi, E ;

Mitelman, A ;

Malovany, S ;

Aurbach, D .

JOURNAL OF SOLID STATE CHEMISTRY, 2006, 179 (06) :1879-1882

[10] On the Way to Rechargeable Mg Batteries: The Challenge of New Cathode Materials [J].

Levi, E. ;

Gofer, Y. ;

Aurbach, D. .

CHEMISTRY OF MATERIALS, 2010, 22 (03) :860-868

← 1 2 →