Confinement of dimeric sulfuric acid in a self-assembled molecular capsule:: [(H2SO4)2⊂(calix[5]arenesulfonic acid)2]

被引：40

作者：

Hardie, MJ ^{[1
]}

Makha, M ^{[1
]}

Raston, CL ^{[1
]}

机构：

[1] Monash Univ, Dept Chem, Melbourne, Vic 3168, Australia

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 23期

关键词：

D O I：

10.1039/a907469d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Self-assembled molecular capsules are formed on crystallisation of calix[5]arenesulfonic acid resulting from treating calix[5]arene with sulfuric acid; the calix[5]arenesulfonic acid molecules dimerise via hydrogen bonding through the sulfonic acid groups, shrouding two hydrogen-bonded sulfuric acid molecules as the supermolecule [(H2SO4)(2)}subset of{(calix[5]arenesulfonic acid)(2)].

引用

页码：2409 / 2410

页数：2

共 35 条

[1] Cyclam as a supramolecular synthon: infinite stacked arrays to encapsulation in superanions [J].

Airey, S ;

Drljaca, A ;

Hardie, MJ ;

Raston, CL .

CHEMICAL COMMUNICATIONS, 1999, (12) :1137-1138

[2]

Atwood J.L., 1993, Supramol. Chem, V2, P309, DOI [10.1080/10610279308029824, DOI 10.1080/10610279308029824]

[3] DOUBLE PARTIAL CONE CONFORMATION FOR NA8(CALIX[6]ARENE SULFONATE).20 5H2O AND ITS PARENT ACID [J].

ATWOOD, JL ;

CLARK, DL ;

JUNEJA, RK ;

ORR, GW ;

ROBINSON, KD ;

VINCENT, RL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (19) :7558-7559

[4] X-RAY-DIFFRACTION EVIDENCE FOR AROMATIC PI HYDROGEN-BONDING TO WATER [J].

ATWOOD, JL ;

HAMADA, F ;

ROBINSON, KD ;

ORR, GW ;

VINCENT, RL .

NATURE, 1991, 349 (6311) :683-684

[5] ORGANIC CLAYS - SYNTHESIS AND STRUCTURE OF NA5[CALIX[4]ARENE SULFONATE].12 H2O, K5[4]ARENE SULFONATE].8 H2O, RB5[CALIX[4]ARENE SULFONATE].5 H2O, AND CS5[CALIX[4]ARENE SULFONATE].4 H2O [J].

ATWOOD, JL ;

COLEMAN, AW ;

ZHANG, H ;

BOTT, SG .

JOURNAL OF INCLUSION PHENOMENA, 1989, 7 (02) :203-211

[6] SYNTHESIS, H-1-NMR, C-13 NMR-SPECTRA AND CONFORMATIONAL PREFERENCE OF OPEN-CHAIN LIGANDS ON LIPOPHILIC MACROCYCLES [J].

BOCCHI, V ;

FOINA, D ;

POCHINI, A ;

UNGARO, R ;

ANDREETTI, GD .

TETRAHEDRON, 1982, 38 (03) :373-378

[7] CALIXARENES, MACROCYCLES WITH (ALMOST) UNLIMITED POSSIBILITIES [J].

BOHMER, V .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (07) :713-745

[8] STRUCTURE OF 4-1 SULFURIC ACID-N,N'-(PARA-PHENYLENE)DIBENZAMIDE COMPLEX, C20H16N2O2.4H2SO4 [J].

CALABRESE, JC ;

GARDNER, KH .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1985, 41 (MAR) :389-392

[9] NOVEL LAYER STRUCTURE OF SODIUM CALIX[4]ARENESULFONATE COMPLEXES - A CLASS OF ORGANIC CLAY MIMICS [J].

COLEMAN, AW ;

BOTT, SG ;

MORLEY, SD ;

MEANS, CM ;

ROBINSON, KD ;

ZHANG, HM ;

ATWOOD, JL .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (10) :1361-1362

[10] Lanthanum(III) capture of 18-crown-6 in the cavity of p-sulfonatocalix[4]arene [J].

Drljaca, A ;

Hardie, MJ ;

Johnson, JA ;

Raston, CL ;

Webb, HR .

CHEMICAL COMMUNICATIONS, 1999, (12) :1135-1136

← 1 2 3 4 →