Wacker-Type Oxidation and Dehydrogenation of Terminal Olefins Using Molecular Oxygen as the Sole Oxidant without Adding Ligand

被引：65

作者：

Wang, Yu-Fei ^{[1
]}

Gao, Ya-Ru ^{[1
]}

Mao, Shuai ^{[1
]}

Zhang, Yan-Lei ^{[1
]}

Guo, Dong-Dong ^{[1
]}

Yan, Zhao-Lei ^{[1
]}

Guo, Shi-Huan ^{[1
]}

Wang, Yong-Qiang ^{[1
]}

机构：

[1] NW Univ Xian, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ, Dept Chem & Mat Sci, Xian 710069, Peoples R China

来源：

ORGANIC LETTERS | 2014年 / 16卷 / 06期

基金：

中国国家自然科学基金;

关键词：

CATALYZED AEROBIC DEHYDROGENATION; SELECTIVE OXIDATION; HYDROGEN-PEROXIDE; EPOXIDATION-ISOMERIZATION; TERT-BUTYLHYDROPEROXIDE; CARBONYL-COMPOUNDS; INTERNAL OLEFINS; FACILE ACCESS; ALKENES; KETONES;

D O I：

10.1021/ol500218p

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient and economical palladium-catalyzed oxidation system has been identified. The oxidation system, characterized by not adding ligand and using molecular oxygen as the sole oxidant, can realize the Tsuji-Wacker oxidation of terminal olefins and especially styrenes to methyl ketones; in addition, this system can achieve tandem Wacker oxidation dehydrogenation of terminal olefins to alpha,beta-unsaturated ketones.

引用

页码：1610 / 1613

页数：4

共 85 条

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