Intramolecular Photoredox Reaction of Naphthoquinone Derivatives

被引：26
|
作者：
Ando, Yoshio [1 ]
Matsumoto, Takashi [1 ]
Suzuki, Keisuke [1 ]
机构：
[1] Tokyo Inst Technol, Dept Chem, Meguro Ku, 2-12-1 O Okayama, Tokyo 1528551, Japan
来源：
SYNLETT | 2017年 / 28卷 / 09期
基金：
日本学术振兴会;
关键词：
naphthoquinone; photochemistry; redox reaction; cyclization; C-H bond functionalization; PRIMARY PHOTOCHEMICAL-REACTIONS; II PHOTOPROCESSES; PHENYL KETONES; DECOMPOSITION; ANTIBIOTICS; HEDAMYCIN; ALDEHYDES;
D O I：
10.1055/s-0036-1589001
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Photoinduced intramolecular redox reaction of naphthoquinone derivatives is described, enabling C-H bond oxygenation at the alpha-position of the quinone nucleus and the quinone reduction under photoirradiation. The substrate scope and mechanistic insight are reported.
引用
收藏
页码：1040 / 1045
页数：6
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