Spectral and electrical properties of ternary (TeO2-V2O5-SM2O3)glasses

被引:93
作者
Turky, G
Dawy, M [1 ]
机构
[1] Natl Res Ctr, Microwave Phys Dept, Cairo, Egypt
[2] Natl Res Ctr, Dept Phys Chem, Cairo, Egypt
关键词
electrical properties; spectral properties; TeO2-V2O5-Sm2O3;
D O I
10.1016/S0254-0584(01)00574-0
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The UV and IR absorption spectra for [65TeO(2)-(35-x)V2O5-xSm(2)O(3)] glasses were measured in the ranges 190-900nm and 1004000 cm(-1), respectively, to obtain information about the structure and the effect of introducing rare earth ions as Sm. The dependence of dielectric constant, dissipation factor, dielectric loss and AC resistivity on frequency, temperature and also on the Sm amount was measured. The results obtained showed that glasses with 4 and 5 mol% Sm2O3 have higher epsilon' and epsilon" due to the weakness of the bonds. Also, the conductivity decreases till about 3 mol% and then increases with the increase of Sm2O3 due to the introduction of Sm ions in the network structure of the glass. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:48 / 59
页数:12
相关论文
共 31 条
[1]   DIELECTRIC PROPERTIES OF THIN FILMS OF ALUMINIUM OXIDE AND SILICON OXIDE [J].
ARGALL, F ;
JONSCHER, AK .
THIN SOLID FILMS, 1968, 2 (03) :185-&
[2]  
BISHAY A, 1966, PHYS CHEM GLASSES, V7, P154
[3]   A GAMMA-RAY INDUCED ABSORPTION BAND IN SOME LEAD BORATE GLASSES [J].
BISHAY, AM .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1960, 43 (08) :417-421
[4]  
Bottcher C. J. F., 1978, THEORY ELECT POLARIZ, VII
[5]   IR TRANSMISSION AND PROPERTIES OF GLASSES IN THE TEO2-[RNOM,RNXM,RN(SO4)M,RN(PO3)M AND B2O3] SYSTEMS [J].
BURGER, H ;
VOGEL, W ;
KOZHUKHAROV, V .
INFRARED PHYSICS, 1985, 25 (1-2) :395-409
[6]   ELECTRICAL CONDUCTION OF ZIRCONIUM OXIDE FILMS [J].
CHAN, WS ;
LOH, CK .
THIN SOLID FILMS, 1970, 6 (02) :91-&
[7]  
CORMIER G, 1993, PHYS REV B, V48, P1690
[8]  
Dieke G.H., 1968, Spectra and Energy Levels of Rare Earth ions in Crystals
[9]  
FLYNN BW, 1981, J PHYS C SOLID STATE, V4, P1005
[10]   POLARIZATION EFFECTS IN THE IONIC CONDUCTIVITY OF SILVER BROMIDE [J].
FRIAUF, RJ .
JOURNAL OF CHEMICAL PHYSICS, 1954, 22 (08) :1329-1338