Green Polycarbonates Prepared by the Copolymerization of CO2 with Epoxides

被引:163
作者
Taherimehr, Masoumeh [1 ]
Pescarmona, Paolo P. [1 ]
机构
[1] Univ Leuven KU Leuven, Ctr Surface Chem & Catalysis, B-3001 Heverlee, Belgium
关键词
biodegradable; catalysts; characterization; copolymers; polycarbonates; properties; CO2/PROPYLENE OXIDE COPOLYMERIZATION; QUATERNARY AMMONIUM-SALTS; BINARY CATALYST SYSTEMS; HIGH-MOLECULAR-WEIGHT; CARBON-DIOXIDE; PROPYLENE-OXIDE; POLY(PROPYLENE CARBONATE); ALTERNATING COPOLYMERIZATION; CYCLOHEXENE OXIDE; STYRENE OXIDE;
D O I
10.1002/app.41141
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Polycarbonates can be prepared by the copolymerization of epoxides with carbon dioxide as an inexpensive, abundant, nontoxic, and renewable feedstock. This review covers the synthesis, the physicochemical properties, and the growing applications of this class of green polymers. The review has been conceived to provide a useful tool for the researchers who are new to this field, as well as to offer an updated overview for those who are already actively working on this topic. (C) 2014 Wiley Periodicals, Inc.
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页数:17
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