Synthetic and Structural Studies on High-Nuclearity Silver Ethynide Cluster Systems

被引：24

作者：

Xie, Yun-Peng ^{[1
,2
,3
]}

Mak, Thomas C. W. ^{[1
,2
]}

机构：

[1] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China

[2] Chinese Univ Hong Kong, Ctr Novel Funct Mol, Shatin, Hong Kong, Peoples R China

[3] Huazhong Univ Sci & Technol, Coll Mat Sci & Engn, Wuhan 430074, Hubei, Peoples R China

来源：

JOURNAL OF CLUSTER SCIENCE | 2014年 / 25卷 / 01期

关键词：

Anionic template; High-nuclearity silver cluster; Phosphonate; Silver ethynide complex; Supramolecular synthon; ACETYLIDE-CONTAINING CLUSTERS; X-RAY-STRUCTURE; NONLINEAR-OPTICAL PROPERTIES; AG-I; CRYSTAL-STRUCTURES; ALKYNYL CAGE; CU-I; ORGANOMETALLIC COMPLEXES; LUMINESCENCE BEHAVIOR; RHOMBOHEDRAL SILVER;

D O I：

10.1007/s10876-013-0651-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A large family of crystalline organometallic compounds with silver ethynide (R-Ca parts per thousand CAg) as a component has been synthesized and characterized. In most cases the R-Ca parts per thousand C- species coordinate to 3-5 silver(I) atoms, which may be symbolized as R-Ca parts per thousand CaS integral Ag (n) (n = 3, 4, 5; R = alkyl, aryl, heteroaryl) by leaving out the charges. In the present review, emphasis is laid on systematic synthetic and structural studies of high-nuclearity silver ethynide clusters, of which the size and shape can be controlled to a certain extent by the judicious choice of templating anions and auxiliary ligands.

引用

页码：189 / 204

页数：16

共 50 条

[31] Visible light photooxidative performance of a high-nuclearity molecular bismuth vanadium oxide cluster
Tucher, Johannes
Streb, Carsten
BEILSTEIN JOURNAL OF NANOTECHNOLOGY, 2014, 5 : 711 - 716
[32] Studies of high-nuclearity lanthanide-titanium oxo clusters: Structure and properties
Zhang, Kai
Du, Shao-Wu
INORGANICA CHIMICA ACTA, 2021, 528
[33] High-Nuclearity Silver Clusters Templated by Carbonates Generated from Atmospheric Carbon Dioxide Fixation
Bian, Shu-Dan
Jia, Jian-Hua
Wang, Quan-Ming
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (10) : 3422 - +
[34] EPR ON THE HIGH-NUCLEARITY PALLADIUM CLUSTER PD561PHEN36O200
DEAGUIAR, JAO
BROM, HB
DEJONGH, LJ
SCHMID, G
ZEITSCHRIFT FUR PHYSIK D-ATOMS MOLECULES AND CLUSTERS, 1989, 12 (1-4): : 457 - 459
[35] Self-assembly and structural transformations of high-nuclearity palladium-rich polyoxometalates
Cameron, Jamie M.
Gao, Jing
Long, De-Liang
Cronin, Leroy
INORGANIC CHEMISTRY FRONTIERS, 2014, 1 (02): : 178 - 185
[36] SYNTHESIS AND CHARACTERIZATION OF A HIGH-NUCLEARITY CLUSTER WITH A (MU-4-OXO)TETRACOBALT(II) CORE
STURGEON, RL
OLMSTEAD, MM
SCHORE, NE
ORGANOMETALLICS, 1991, 10 (06) : 1649 - 1651
[37] High-Nuclearity (Cu8-Based) Cage Silsesquioxanes: Synthesis and Structural Study
Bilyachenko, Alexey N.
Khrustalev, Victor N.
Zubavichus, Yan V.
Vologzhanina, Anna V.
Astakhov, Grigorii S.
Gutsul, Evgenii I.
Shubina, Elena S.
Levitsky, Mikhail M.
CRYSTAL GROWTH & DESIGN, 2018, 18 (04) : 2452 - 2457
[38] Construction of High-Nuclearity Manganese-Cluster Organic Frameworks by Using a Tripodal Alcohol Ligand
Ma, Xiang
Zhao, Dan
Lin, Li-Fen
Qin, Shao-Jie
Zheng, Wen-Xu
Qi, Yan-Jie
Li, Xin-Xiong
Zheng, Shou-Tian
INORGANIC CHEMISTRY, 2016, 55 (21) : 11311 - 11315
[39] Tetrahedral-Shaped Anions as a Template in the Synthesis of High-Nuclearity Silver(I) Dithiophosphate Clusters
Liao, Jian-Hong
Chang, How-Wei
You, Hong-Chih
Fang, Ching-Shiang
Liu, C. W.
INORGANIC CHEMISTRY, 2011, 50 (06) : 2070 - 2072
[40] THEORETICAL AND STRUCTURAL STUDIES ON HIGH NUCLEARITY CLUSTERS
MICHAEL, D
MINGOS, P
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1991, 201 : 470 - INOR

← 1 2 3 4 5 →