Synthetic and Structural Studies on High-Nuclearity Silver Ethynide Cluster Systems

被引：24

作者：

Xie, Yun-Peng ^{[1
,2
,3
]}

Mak, Thomas C. W. ^{[1
,2
]}

机构：

[1] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China

[2] Chinese Univ Hong Kong, Ctr Novel Funct Mol, Shatin, Hong Kong, Peoples R China

[3] Huazhong Univ Sci & Technol, Coll Mat Sci & Engn, Wuhan 430074, Hubei, Peoples R China

来源：

JOURNAL OF CLUSTER SCIENCE | 2014年 / 25卷 / 01期

关键词：

Anionic template; High-nuclearity silver cluster; Phosphonate; Silver ethynide complex; Supramolecular synthon; ACETYLIDE-CONTAINING CLUSTERS; X-RAY-STRUCTURE; NONLINEAR-OPTICAL PROPERTIES; AG-I; CRYSTAL-STRUCTURES; ALKYNYL CAGE; CU-I; ORGANOMETALLIC COMPLEXES; LUMINESCENCE BEHAVIOR; RHOMBOHEDRAL SILVER;

D O I：

10.1007/s10876-013-0651-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A large family of crystalline organometallic compounds with silver ethynide (R-Ca parts per thousand CAg) as a component has been synthesized and characterized. In most cases the R-Ca parts per thousand C- species coordinate to 3-5 silver(I) atoms, which may be symbolized as R-Ca parts per thousand CaS integral Ag (n) (n = 3, 4, 5; R = alkyl, aryl, heteroaryl) by leaving out the charges. In the present review, emphasis is laid on systematic synthetic and structural studies of high-nuclearity silver ethynide clusters, of which the size and shape can be controlled to a certain extent by the judicious choice of templating anions and auxiliary ligands.

引用

页码：189 / 204

页数：16

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