Sm3S3BO3: The First Sulfide Borate without S-O and B-S Bonds

被引：41

作者：

Guo, Sheng-Ping ^{[1
]}

Chi, Yang ^{[1
]}

Xue, Huai-Guo ^{[1
]}

机构：

[1] Yangzhou Univ, Coll Chem & Chem Engn, Yangzhou 225002, Jiangsu, Peoples R China

来源：

INORGANIC CHEMISTRY | 2015年 / 54卷 / 23期

基金：

中国国家自然科学基金;

关键词：

NONLINEAR-OPTICAL MATERIALS; LN;

D O I：

10.1021/acs.inorgchem.5b01930

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An unprecedented quaternary sulfide borate, Sm3S3BO3 (1), was obtained via a high-temperature solid-state synthesis method. It crystallizes in the triclinic space group P (1) over bar, and its 3D structure features a 2D (Sm2S2)(infinity) wrinkled layer and a 1D (SmS)(infinity) ladderlike chain bridged by trigonal-planar (BO3)(3-) through Sm-O bonds, demonstrating the first sulfide borate without S-O and B-S bonds. Its optical energy gap is measured to be around 2.5 eV and verified by electronic structure calculation.

引用

页码：11052 / 11054

页数：3

共 19 条

[1]

[Anonymous], 2015, Angew. Chem, DOI DOI 10.1002/ANGE.201409837

[2] Metal Chalcogenides: A Rich Source of Nonlinear Optical Materials [J].

Chung, In ;

Kanatzidis, Mercouri G. .

CHEMISTRY OF MATERIALS, 2014, 26 (01) :849-869

[3] Crystal structure and magnetic and photocatalytic properties of a new ternary rare-earth mixed chalcogenide, Dy4S4Te3 [J].

Guo, Sheng-Ping ;

Guo, Guo-Cong .

JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (48) :20621-20628

[4] Novel single-crystal's voltage-dependent effect and magnetic order of Ln2ZrQ5 (Ln = La, Sm, Gd; Q = S, Se) semiconductors [J].

Guo, Sheng-Ping ;

Wang, Guan-E ;

Zhang, Ming-Jian ;

Wu, Mei-Feng ;

Liu, Guang-Ning ;

Jiang, Xiao-Ming ;

Guo, Guo-Cong ;

Huang, Jin-Shun .

DALTON TRANSACTIONS, 2013, 42 (08) :2679-2682

[5] A Series of New Infrared NLO Semiconductors, ZnY6Si2S14, AlxDy3(SiyAl1-y)S7, and Al0.33Sm3SiS7 [J].

Guo, Sheng-Ping ;

Guo, Guo-Cong ;

Wang, Ming-Sheng ;

Zou, Jian-Ping ;

Xu, Gang ;

Wang, Guo-Jian ;

Long, Xi-Fa ;

Huang, Jin-Shun .

INORGANIC CHEMISTRY, 2009, 48 (15) :7059-7065

[6] A facile approach to hexanary chalcogenoborate featuring a 3-D chiral honeycomb-like open-framework constructed from rare-earth consolidating thiogallate-closo-dodecaborate [J].

Guo, Sheng-Ping ;

Guo, Guo-Cong ;

Wang, Ming-Sheng ;

Zou, Jian-Ping ;

Zeng, Hui-Yi ;

Cai, Li-Zhen ;

Huang, Jin-Shun .

CHEMICAL COMMUNICATIONS, 2009, (29) :4366-4368

[7] The First Borosulfate K5[B(SO4)4] [J].

Hoeppe, Henning A. ;

Kazmierczak, Karolina ;

Daub, Michael ;

Foerg, Katharina ;

Fuchs, Franziska ;

Hillebrecht, Harald .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (25) :6255-6257

[8] NaSr3Be3B3O9F4: A Promising Deep-Ultraviolet Nonlinear Optical Material Resulting from the Cooperative Alignment of the [Be3B3O12F]10- Anionic Group [J].

Huang, Hongwei ;

Yao, Jiyong ;

Lin, Zheshuai ;

Wang, Xiaoyang ;

He, Ran ;

Yao, Wenjiao ;

Zhai, Naixia ;

Chen, Chuangtian .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (39) :9141-9144

[9] Pb2B5O9I: An Iodide Borate with Strong Second Harmonic Generation [J].

Huang, Yi-Zhi ;

Wu, Li-Ming ;

Wu, Xin-Tao ;

Li, Long-Hua ;

Chen, Ling ;

Zhang, Yong-Fan .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (37) :12788-12789

[10] Large Crystal Growth and New Crystal Exploration of Mid-Infrared Second-Order Nonlinear Optical Materials [J].

Jiang, Xiao-Ming ;

Guo, Sheng-Ping ;

Zeng, Hui-Yi ;

Zhang, Ming-Jian ;

Guo, Guo-Cong .

STRUCTURE-PROPERTY RELATIONSHIPS IN NON-LINEAR OPTICAL CRYSTALS II: THE IR REGION, 2012, 145 :1-43

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