Two new insecticidal sesquiterpene polyol esters from Celastrus angulatus

被引：14
作者：
Wang, M
Wu, WJ
Zhu, JN
Ji, ZQ
Zhou, WM
机构：
[1] China Agr Univ, Dept Appl Chem, Beijing 100094, Peoples R China
[2] Northwestern Agr Univ, Dept Plant Protect, Yangling 712100, Shaanxi, Peoples R China
来源：
NATURAL PRODUCT RESEARCH | 2006年 / 20卷 / 07期
基金：
中国国家自然科学基金;
关键词：
Celastrus angulatus; Celastraceae; insecticide; beta-dihydroagarofuran sesquiterpene; celangulatin;
D O I：
10.1080/14786410500161056
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Two new insecticidal sesquiterpene polyol esters with a β-dihydroagarofuran sesquiterpene skeleton, celangulatin A (1), B (2), and two known compounds, celangulin IV (3) and V (4), were isolated from the leaves of Celastrus angulatus by bioassay-guided fractionation. Their chemical structures were elucidated mainly by analyses of the NMR and MS spectral data. Their insecticidal activities against Mythimna separate were demonstrated with the KD50 value of 68.5 and 215.8 μg g-1 respectively. © 2006 Taylor & Francis.
引用
收藏
页码：653 / 658
页数：6
相关论文
共 25 条
[1]  
AYSEN Y, 1998, PHYTOCHEMISTRY, V48, P863
[2]  
BRUNING R, 1978, PHYTOCHEMISTRY, V17, P1821, DOI 10.1016/S0031-9422(00)88719-1
[3]   Fuzzy risk analysis based on similarity measures of generalized fuzzy numbers [J].
Chen, SJ ;
Chen, SM .
IEEE TRANSACTIONS ON FUZZY SYSTEMS, 2003, 11 (01) :45-56
[4]   Immunosuppressive sesquiterpene alkaloids from Tripterygium wilfordii [J].
Duan, HQ ;
Takaishi, Y ;
Momota, H ;
Ohmoto, Y ;
Taki, T ;
Jia, YF ;
Li, D .
JOURNAL OF NATURAL PRODUCTS, 2001, 64 (05) :582-587
[5]   Sesquiterpene alkaloids from Tripterygium hypoglaucum and Tripterygium wilfordii:: A new class of potent anti-HIV agents [J].
Duan, HQ ;
Takaishi, Y ;
Imakura, Y ;
Jia, YF ;
Li, D ;
Cosentino, LM ;
Lee, KH .
JOURNAL OF NATURAL PRODUCTS, 2000, 63 (03) :357-361
[6]   Sesquiterpene evoninate alkaloids from Tripterygium hypoglaucum [J].
Duan, HQ ;
Takaishi, Y .
PHYTOCHEMISTRY, 1999, 52 (08) :1735-1738
[7]  
JACOBSON M, 1958, AGR HDB USDA, V154, P44
[8]   Variable cytokeratin 7/20 profiles in carcinomas involving the liver [J].
Kim, MK ;
Park, CK .
APPLIED IMMUNOHISTOCHEMISTRY & MOLECULAR MORPHOLOGY, 1999, 7 (01) :52-57
[9]   New triterpenoids from the leaves of Abrus precatorius [J].
Kim, NC ;
Kim, DSHL ;
Kinghorn, AD .
NATURAL PRODUCT LETTERS, 2002, 16 (04) :261-266
[10]   A new sesquiterpene ester from Celastrus orbiculatus reversing multidrug resistance in cancer gels [J].
Kim, SE ;
Kim, YH ;
Lee, JJ ;
Kim, YC .
JOURNAL OF NATURAL PRODUCTS, 1998, 61 (01) :108-111
123