Synthesis, structure and properties of a novel 3D pentanuclear [Zn5(OH)2]8+ cluster-based (3,4,11)-connected coordination polymer

被引：3
|
作者：
Kan, Wei-Qiu [1 ]
Wen, Shi-Zheng [1 ,2 ]
Kan, Yu-He [1 ]
Hu, Hua-You [1 ]
Yang, Lin [1 ]
Li, Dan [1 ]
机构：
[1] Huaiyin Normal Univ, Sch Chem & Chem Engn, Jiangsu Prov Key Lab Chem Low Dimens Mat, Huaian 223300, Peoples R China
[2] Huaiyin Normal Univ, Huaian Key Lab Funct Mat Informat, Sch Phys & Elect Elect Engn, Huaian 223300, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2015年 / 61卷
基金：
美国国家科学基金会;
关键词：
Pentanuclear cluster; Highly connected; Coordination polymer; Optical band gap; Photoluminescence; METAL-ORGANIC FRAMEWORKS; 2ND-ORDER NONLINEAR OPTICS; PHOTOLUMINESCENT PROPERTIES; LIGAND; SERIES; PHOTOCATALYSIS; LUMINESCENCE; LINKER;
D O I：
10.1016/j.inoche.2015.08.026
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel coordination polymer based on the multidentate N-donor ligand 14(1H-1,2,4-triazol-1-yOmethyl)-3,5-bis(3-pyridy1)-1,2,4-triazole (3,3'-tmbpt) and 1,2,4,5-benzenetetracarboxylate anion (btec), namely, [Zn-5(3,3'-tmbpt)(btec)(2)(OH)(2)] (1), has been synthesized hydrothermally. Compound 1 displays a rare 3D (3,4,11)-connected framework based on a [Zn-5(OH)(2)](8+) cluster. The optical band gap and photoluminescent property of compound 1 have been studied. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：85 / 88
页数：4
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