Synthesis and properties of phases in the system BaCO3-PbO-Nb2O5

被引：0

作者：

Shtin, SA ^{[1
]}

Podkorytov, AL ^{[1
]}

Zhukovskii, VM ^{[1
]}

Sokolova, EV ^{[1
]}

Kudakaeva, SR ^{[1
]}

机构：

[1] Ural State Univ, Ekaterinburg 620083, Russia

来源：

INORGANIC MATERIALS | 2004年 / 40卷 / 04期

基金：

俄罗斯基础研究基金会;

关键词：

Electrical Conductivity; Solid Solution; Barium; Acid Medium; Structure Type;

D O I：

10.1023/B:INMA.0000023968.67549.54

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The phase formation kinetics and phase relations in the BaCO3-PbO-Nb2O5 system are studied. Barium lead niobates are prepared by solid-state reactions, and the composition ranges of solid solutions with different structures are determined. All of the materials are examined by x-ray diffraction, and their stability in acid media is assessed. The electrical conductivity of the Pb-containing niobates is measured. The results are used to analyze property-structure-composition relations. Based on the phase-equilibrium data and the chemical stability and electrical properties of the niobates, the structure types and compositions of niobates are identified which are the most attractive for producing ion-selective materials.

引用

页码：415 / 419

页数：5

共 10 条

[1]

CAMMAN K, 1977, ARBEITEN IONESELEKTI

[2]

Delmon B., 1969, INTRO CINETIQUE HETE

[3]

NEIMAN AY, 1987, ZH NEORG KHIM+, V32, P359

[4]

NIKOLSKII VP, 1980, IONOSELEKTIVNYE ELEK

[5]

PODKORYTOV AL, 2000, 5 MEZHD SOV FUND PRO, P150

[6]

PODKORYTOV AL, 2002, ZH NEORG KHIM, V47, P1782

[7]

PODKORYTOV AL, 1999, ZH NEORG KHIM, V44, P855

[8]

SOKOLOVA EV, 2002, 8 VSER SOV VYS PER K, P170

[9]

VOLKOV VL, 1997, ZH ANAL KHIM, V52, P844

[10]

ZHUKOVSKII VM, 2002, VER K AKT PROBL AN K, V2, P158

← 1 →