Synthesis, characterization, and biological activity of Cd(II) and Mn(II) coordination polymers based on pyridine-2,6-dicarboxylic acid

被引:9
作者
Etaiw, S. E. H. [1 ]
El-Bendary, M. M. [1 ,2 ]
Abdelazim, H. [1 ]
机构
[1] Tanta Univ, Fac Sci, Dept Chem, Tanta, Egypt
[2] Univ Jeddah, Fac Sci, Dept Chem, Jeddah, Saudi Arabia
关键词
Cd(II) and Mn(II); coordination polymers; pyridine-2,6-dicarboxylic acid; spectra; antimicrobial activities; METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURE; PHOTOLUMINESCENT PROPERTIES; COMPLEXES; LIGANDS; STORAGE; CATION; AGENT;
D O I
10.1134/S1070328417050013
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The coordination polymers (CPs) {[Cd(Pydc)(H2O)(3)] center dot PydcH(2)} (I) and [Mn(Pydc)(H2O)(3)] center dot PydcH2} (II) were obtained by the reaction of CdSO4 center dot 5H(2)O or MnCl2 center dot 4H(2)O with pyridine-2,6-dicarboxylic acid (PydcH(2)). The structures of the CPs I and II were characterized by IR, UV-Vis, TGA, and X-ray single crystal analysis (CIF files CCDC nos. 1417757 (I), 1417758 (II)). The network structures of I and II are constructed by an infinite number of discrete binuclear molecules and free PydcH2. The structures of the CPs I and II connected by the extensive H-bonds and pi-pi stacking, forming a 3D-network. The CPs I and II were screened to test their antimicrobial activities against different species of bacteria and fungi.
引用
收藏
页码:320 / 330
页数:11
相关论文
共 47 条
  • [1] Synthesis, Characterization, Crystal Structures, and Solution Studies of Ni(II), Cu(II) and Zn(II) Complexes Obtained from Pyridine-2,6-dicarboxylic Acid and 2,9-Dimethyl-1,10-Phenanthroline
    Aghabozorga, H.
    Sadr-khanlou, E.
    Shokrollahi, A.
    Ghaedi, M.
    Shamsipur, M.
    [J]. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2009, 6 (01) : 55 - 70
  • [2] Chromium(III) and Calcium(II) Complexes Obtained from Dipicolinic Acid: Synthesis, Characterization, X-Ray Crystal Structure and Solution Studies
    Aghajani, Z.
    Aghabozorg, H.
    Sadr-Khanlou, E.
    Shokrollahi, A.
    Derki, S.
    Shamsipur, M.
    [J]. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2009, 6 (02) : 373 - 385
  • [3] Synthesis and hydrogen adsorption properties of internally polarized 2,6-azulenedicarboxylate based metal-organic frameworks
    Barman, Samir
    Khutia, Anupam
    Koitz, Ralph
    Blacque, Olivier
    Furukawa, Hiroyasu
    Iannuzzi, Marcella
    Yaghi, Omar M.
    Janiak, Christoph
    Hutter, Juerg
    Berke, Heinz
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (44) : 18823 - 18830
  • [4] Binary Superlattices from Colloidal Nanocrystals and Giant Polyoxometalate Clusters
    Bodnarchuk, Maryna I.
    Erni, Rolf
    Krumeich, Frank
    Kovalenko, Maksym V.
    [J]. NANO LETTERS, 2013, 13 (04) : 1699 - 1705
  • [5] COORDINATIVE BINDING OF DIVALENT CATIONS WITH LIGANDS RELATED TO BACTERIAL SPORES - EQUILIBRIUM STUDIES
    CHUNG, L
    RAJAN, KS
    MERDINGER, E
    GRECZ, N
    [J]. BIOPHYSICAL JOURNAL, 1971, 11 (06) : 469 - +
  • [6] DEPENDENCE OF THE HEAT RESISTANCE OF BACTERIAL ENDOSPORES ON THEIR DIPICOLINIC ACID CONTENT
    CHURCH, BD
    HALVORSON, H
    [J]. NATURE, 1959, 183 (4654) : 124 - 125
  • [7] Dynamic magnetic MOFs
    Coronado, Eugenio
    Minguez Espallargas, Guillermo
    [J]. CHEMICAL SOCIETY REVIEWS, 2013, 42 (04) : 1525 - 1539
  • [8] RELATIONSHIPS BETWEEN THE CARBON-OXYGEN STRETCHING FREQUENCIES OF CARBOXYLATO COMPLEXES AND THE TYPE OF CARBOXYLATE COORDINATION
    DEACON, GB
    PHILLIPS, RJ
    [J]. COORDINATION CHEMISTRY REVIEWS, 1980, 33 (03) : 227 - 250
  • [9] Ruthenium(II) complexes containing bidentate Schiff bases and their antifungal activity
    Dharmaraj, N
    Viswanathamurthi, P
    Natarajan, K
    [J]. TRANSITION METAL CHEMISTRY, 2001, 26 (1-2) : 105 - 109
  • [10] STUDIES ON CO-ORDINATION COMPLEXES OF SILVER(II) .4. CRYSTAL AND MOLECULAR STRUCTURE OF SILVER(II) BIS(PYRIDINE-2,6-DICARBOXYLATE) MONOHYDRATE
    DREW, MGB
    MATTHEWS, RW
    WALTON, RA
    [J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (09): : 1405 - &