The crystal, molecular and electronic structure of [ReBr2(NO)(CO)(PPh3)2]•NO complex

被引：0
作者：
Bartczak, TJ
Czurak, W
Dziegielewski, JO
Machura, B
Kusz, J
Warczewski, J
机构：
[1] Lodz Tech Univ, Inst Gen & Ecol Chem, Xray Crystallog Lab, PL-90924 Lodz, Poland
[2] Silesian Univ, Inst Phys, PL-40006 Katowice, Poland
[3] Silesian Univ, Dept Inorgan & Radiat Chem, Inst Chem, PL-40006 Katowice, Poland
来源：
POLISH JOURNAL OF CHEMISTRY | 2000年 / 74卷 / 02期
关键词：
rhenium; nitrosyl; X-ray structure; electronic structure; nitric oxide;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new rhenium nitrosyl complex [ReBr2(NO)(CO)(PPh3)(2)]. NO has been synthesized and characterized by X-ray diffraction, IR, UV-Vis and magnetochemical measurements. The Re atom is of six-coordinate distorted octahedral configuration and linear nitrosyl ligand is trans towards the bromine ligand and cis towards CO molecule.
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页码：265 / 273
页数：9
相关论文
共 17 条
  • [11] DZIEGIELEWSKI JO, 1995, SPECTROSCOPY OF BIOLOGICAL MOLECULES, P589
  • [12] PREPARATION AND SPECTROSCOPIC CHARACTERIZATION OF [RE(NO)(2)X(2)L(2)] (X=CL, BR, I, L(2)=2PPH(3), DPPE) - APPLICATION OF [RE(NO)(2)BR(2)L(2)] IN OXIDATION OF OLEFINS
    DZIEGIELEWSKI, JO
    FILIPEK, K
    MACHURA, B
    [J]. POLYHEDRON, 1995, 14 (04) : 555 - 561
  • [13] CHEMISTRY OF (CARBONYL)(NITROSYL)[BIS(PHOSPHORUS DONOR)]RHENIUM COMPLEXES
    HUND, HU
    RUPPLI, U
    BERKE, H
    [J]. HELVETICA CHIMICA ACTA, 1993, 76 (02) : 963 - 975
  • [14] Lever A.B. P., 1984, Inorganic Electronic Spectroscopy, V2nd
  • [15] RICHTERADDO GB, 1992, METAL NETROSYLS
  • [16] Sheldrick G. M., 1990, SHELXTL
  • [17] Sheldrick GM, 1997, SHELXL 97 PROGRAM SO
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