The crystal, molecular and electronic structure of [ReBr2(NO)(CO)(PPh3)2]•NO complex

被引:0
作者
Bartczak, TJ
Czurak, W
Dziegielewski, JO
Machura, B
Kusz, J
Warczewski, J
机构
[1] Lodz Tech Univ, Inst Gen & Ecol Chem, Xray Crystallog Lab, PL-90924 Lodz, Poland
[2] Silesian Univ, Inst Phys, PL-40006 Katowice, Poland
[3] Silesian Univ, Dept Inorgan & Radiat Chem, Inst Chem, PL-40006 Katowice, Poland
关键词
rhenium; nitrosyl; X-ray structure; electronic structure; nitric oxide;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new rhenium nitrosyl complex [ReBr2(NO)(CO)(PPh3)(2)]. NO has been synthesized and characterized by X-ray diffraction, IR, UV-Vis and magnetochemical measurements. The Re atom is of six-coordinate distorted octahedral configuration and linear nitrosyl ligand is trans towards the bromine ligand and cis towards CO molecule.
引用
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页码:265 / 273
页数:9
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