Gross alpha determination in drinking water using a highly specific resin and LSC

被引:17
作者
Happel, S
Letessier, P
Ensinger, W
Eikenberg, JH
Thakkar, AH
Horwitz, EP
机构
[1] Eichrom Europe, F-35170 Bruz, France
[2] Eichrom Technol, Darien, IL 60561 USA
[3] Univ Marburg, Fachbereich Chem, D-35043 Marburg, Germany
[4] Paul Scherrer Inst, CH-5232 Villigen, Switzerland
关键词
drinking water; gross alpha; alpha-/beta-discrimination LSC; extraction chromatography;
D O I
10.1016/j.apradiso.2004.03.005
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Some results of experiments concerning a new highly specific resin for the extraction of alpha-emitting nuclides from drinking water samples are presented. The product used during these experiments is a new extraction chromatographic resin which consists of a combination of several reagents and extractants supported on inert polymeric substrates, called "Resin" hereafter. It shows strong affinity for Actinides in the tri-, tetra- and hexavalent oxidation state, as well as for radium, even in presence of large amounts of calcium. Gross-alpha activities were determined using alpha-/beta-discrimination liquid scintillation counting (alpha-/beta-LSC) by direct measurement of the dried resin after extraction. Counting conditions were optimised accordingly. A method for the determination of alpha-emitting nuclides in drinking water was developed and tested using intercomparison and spiked drinking water samples. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:339 / 344
页数:6
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