Lithium Recovery from Aqueous Resources and Batteries: A Brief Review A review of the methods to produce lithium and approaches to recycling from end-of-life lithium-ion batteries

被引:130
作者
Li, Ling [1 ]
Deshmane, Vishwanath G. [2 ]
Paranthaman, M. Parans [1 ]
Bhave, Ramesh [2 ]
Moyer, Bruce A. [1 ]
Harrison, Stephen [3 ]
机构
[1] Oak Ridge Natl Lab, Chem Sci Div, Oak Ridge, TN 37831 USA
[2] Oak Ridge Natl Lab, Mat Sci & Technol Div, Oak Ridge, TN 37831 USA
[3] Alger Alternat Energy LLC, Brawley, CA 92227 USA
来源
JOHNSON MATTHEY TECHNOLOGY REVIEW | 2018年 / 62卷 / 02期
关键词
SALT LAKE BRINE; LAYERED DOUBLE HYDROXIDES; SOLID-PHASE REACTION; MANGANESE OXIDE; ADSORPTION PROPERTIES; SOLVENT-EXTRACTION; LIQUID-MEMBRANE; METAL VALUES; HYDROMETALLURGICAL PROCESS; H2TIO3-LITHIUM ADSORBENT;
D O I
10.1595/205651317X696676
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The demand for lithium is expected to increase drastically in the near future due to the increased usage of rechargeable lithium-ion batteries (LIB) in electric vehicles, smartphones and other portable electronics. To alleviate the potential risk of undersupply, lithium can be extracted from raw sources consisting of minerals and brines or from recycled batteries and glasses. Aqueous lithium mining from naturally occurring brines and salt deposits is advantageous compared to extraction from minerals, since it may be more environmentally friendly and cost-effective. In this article, we briefly discuss the adsorptive behaviour, synthetic methodology and prospects or challenges of major sorbents including spinel lithium manganese oxide (Li-Mn-O or LMO), spinel lithium titanium oxide (Li-Ti-O or LTO) and lithium aluminium layered double hydroxide chloride (LiCl.2Al(OH)(3)). Membrane approaches and lithium recovery from end-of-life LIB will also be briefly discussed.
引用
收藏
页码:161 / 176
页数:16
相关论文
共 110 条
[1]   Recovery of lithium from Uyuni salar brine [J].
An, Jeon Woong ;
Kang, Dong Jun ;
Khuyen Thi Tran ;
Kim, Myong Jun ;
Lim, Tuti ;
Tam Tran .
HYDROMETALLURGY, 2012, 117 :64-70
[2]   Probing the local structure and the role of protons in lithium sorption processes of a new lithium-rich manganese oxide [J].
Ariza, MJ ;
Jones, DJ ;
Rozière, J ;
Chitrakar, R ;
Ooi, K .
CHEMISTRY OF MATERIALS, 2006, 18 (07) :1885-1890
[3]   An innovative approach to recover the metal values from spent lithium-ion batteries [J].
Barik, S. P. ;
Prabaharan, G. ;
Kumar, B. .
WASTE MANAGEMENT, 2016, 51 :222-226
[4]  
Bauman W.C., 2001, US Patent, Patent No. 6280693
[5]   Synthesis and structure of the gibbsite intercalation compounds [LiAl2(OH)(6)]X {X=Cl, Br, NO3} and [LiAl2(OH)(6)]Cl center dot H2O using synchrotron X-ray and neutron powder diffraction [J].
Besserguenev, AV ;
Fogg, AM ;
Francis, RJ ;
Price, SJ ;
OHare, D ;
Isupov, VP ;
Tolochko, BP .
CHEMISTRY OF MATERIALS, 1997, 9 (01) :241-247
[6]  
Bhave R., 2018, SELECTIVE RECO UNPUB
[7]   Study on the recovery of lithium from high Mg2+/Li+ ratio brine by nanofiltration [J].
Bi, Qiuyan ;
Zhang, Zhiqiang ;
Zhao, Chenying ;
Tao, Zhenqi .
WATER SCIENCE AND TECHNOLOGY, 2014, 70 (10) :1690-1694
[8]  
Boryta D. A., 2011, US Patent Appl, Patent No. [2011/0,123,427, 20110123427]
[9]  
Burba J.L., 2015, Patent No. [WO 2015/171109 A1, 2015171109]
[10]   Advances in the recovering of spent lithium battery compounds [J].
Castillo, S ;
Ansart, F ;
Laberty-Robert, C ;
Portal, J .
JOURNAL OF POWER SOURCES, 2002, 112 (01) :247-254