Synthesis of a Covalent Monolayer Sheet by Photochemical Anthracene Dimerization at the Air/Water Interface and its Mechanical Characterization by AFM Indentation

被引：146

作者：

Payamyar, Payam ^{[1
]}

Kaja, Khaled ^{[2
]}

Ruiz-Vargas, Carlos ^{[2
]}

Stemmer, Andreas ^{[2
]}

Murray, Daniel J. ^{[3
]}

Johnson, Carey J. ^{[3
]}

King, Benjamin T. ^{[3
]}

Schiffmann, Florian ^{[4
]}

VandeVondele, Joost ^{[4
]}

Renn, Alois ^{[5
]}

Goetzinger, Stephan ^{[6
]}

Ceroni, Paola ^{[7
]}

Schuetz, Andri ^{[1
]}

Lee, Lay-Theng ^{[8
]}

Zheng, Zhikun ^{[1
]}

Sakamoto, Junji ^{[1
]}

Schlueter, A. Dieter ^{[1
]}

机构：

[1] ETH, Dept Mat, Polymer Chem Grp, Swiss Fed Inst Technol, CH-8093 Zurich, Switzerland

[2] ETH, Nanotechnol Grp, CH-8093 Zurich, Switzerland

[3] Univ Nevada, Dept Chem, Reno, NV 89557 USA

[4] ETH, CH-8093 Zurich, Switzerland

[5] ETH, Phys Chem Lab, CH-8093 Zurich, Switzerland

[6] Max Planck Inst Sci Light, Erlangen, Germany

[7] Univ Bologna, Dept Chem G Ciamician, Bologna, Italy

[8] CEA Saclay, Lab Leon Brillouin CEA CNRS, F-91191 Gif Sur Yvette, France

来源：

ADVANCED MATERIALS | 2014年 / 26卷 / 13期

关键词：

nanosheets; networks; monolayers; synthesis; nanoindentation; 2-DIMENSIONAL POLYMERS; ORGANOMETALLIC SHEETS; ELASTIC PROPERTIES; BULK SYNTHESIS; GRAPHENE; PHOTODIMERIZATION; ADSORPTION; FIELD; POLY(N-ISOPROPYLACRYLAMIDE); LUMINESCENCE;

D O I：

10.1002/adma.201304705

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Covalent monolayer sheets in 2 hours: spreading of threefold anthracene-equipped shape-persistent and amphiphilic monomers at the air/water interface followed by a short photochemical treatment provides access to infinitely sized, strictly monolayered, covalent sheets with in-plane elastic modulus in the range of 19 N/m. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：2052 / 2058

页数：7

共 92 条

[91] An efficient a Posteriori treatment for dispersion interaction in density-functional-based tight binding [J].

Zhechkov, L ;

Heine, T ;

Patchkovskii, S ;

Seifert, G ;

Duarte, HA .

JOURNAL OF CHEMICAL THEORY AND COMPUTATION, 2005, 1 (05) :841-847

[92] Square-Micrometer-Sized, Free-Standing Organometallic Sheets and Their Square-Centimeter-Sized Multilayers on Solid Substrates [J].

Zheng, Zhikun ;

Ruiz-Vargas, Carlos S. ;

Bauer, Thomas ;

Rossi, Antonella ;

Payamyar, Payam ;

Schuetz, Andri ;

Stemmer, Andreas ;

Sakamoto, Junji ;

Schlueter, A. Dieter .

MACROMOLECULAR RAPID COMMUNICATIONS, 2013, 34 (21) :1670-1680

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