Synthesis of a Covalent Monolayer Sheet by Photochemical Anthracene Dimerization at the Air/Water Interface and its Mechanical Characterization by AFM Indentation

被引：146

作者：

Payamyar, Payam ^{[1
]}

Kaja, Khaled ^{[2
]}

Ruiz-Vargas, Carlos ^{[2
]}

Stemmer, Andreas ^{[2
]}

Murray, Daniel J. ^{[3
]}

Johnson, Carey J. ^{[3
]}

King, Benjamin T. ^{[3
]}

Schiffmann, Florian ^{[4
]}

VandeVondele, Joost ^{[4
]}

Renn, Alois ^{[5
]}

Goetzinger, Stephan ^{[6
]}

Ceroni, Paola ^{[7
]}

Schuetz, Andri ^{[1
]}

Lee, Lay-Theng ^{[8
]}

Zheng, Zhikun ^{[1
]}

Sakamoto, Junji ^{[1
]}

Schlueter, A. Dieter ^{[1
]}

机构：

[1] ETH, Dept Mat, Polymer Chem Grp, Swiss Fed Inst Technol, CH-8093 Zurich, Switzerland

[2] ETH, Nanotechnol Grp, CH-8093 Zurich, Switzerland

[3] Univ Nevada, Dept Chem, Reno, NV 89557 USA

[4] ETH, CH-8093 Zurich, Switzerland

[5] ETH, Phys Chem Lab, CH-8093 Zurich, Switzerland

[6] Max Planck Inst Sci Light, Erlangen, Germany

[7] Univ Bologna, Dept Chem G Ciamician, Bologna, Italy

[8] CEA Saclay, Lab Leon Brillouin CEA CNRS, F-91191 Gif Sur Yvette, France

来源：

ADVANCED MATERIALS | 2014年 / 26卷 / 13期

关键词：

nanosheets; networks; monolayers; synthesis; nanoindentation; 2-DIMENSIONAL POLYMERS; ORGANOMETALLIC SHEETS; ELASTIC PROPERTIES; BULK SYNTHESIS; GRAPHENE; PHOTODIMERIZATION; ADSORPTION; FIELD; POLY(N-ISOPROPYLACRYLAMIDE); LUMINESCENCE;

D O I：

10.1002/adma.201304705

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Covalent monolayer sheets in 2 hours: spreading of threefold anthracene-equipped shape-persistent and amphiphilic monomers at the air/water interface followed by a short photochemical treatment provides access to infinitely sized, strictly monolayered, covalent sheets with in-plane elastic modulus in the range of 19 N/m. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：2052 / 2058

页数：7

共 92 条

[1] Single Layer of Polymeric Fe-Phthalocyanine: An Organometallic Sheet on Metal and Thin Insulating Film [J].

Abel, Mathieu ;

Clair, Sylvain ;

Ourdjini, Oualid ;

Mossoyan, Mireille ;

Porte, Louis .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (05) :1203-1205

[2]

Accelrys Software Inc, 2010, MAT STUD REL 5 5

[3] Excimer formation in the interlayer region of arene-derivatized zirconium phosphonates [J].

Amicangelo, JC ;

Leenstra, WR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (48) :14698-14699

[4]

[Anonymous], SYNTHESIS POLYM NEW

[5]

[Anonymous], CHEM EUR J

[6]

[Anonymous], 2009, Photochemistry of Organic Compounds: from Concepts to Practice, DOI DOI 10.1021/CR60290A001

[7] TEMPLATE SYNTHESIS OF 2-DIMENSIONAL NETWORK OF CROSS-LINKED ACRYLATE POLYMER IN A CAST MULTIBILAYER FILM [J].

ASAKUMA, S ;

OKADA, H ;

KUNITAKE, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (05) :1749-1755

[8] Synthesis of Free-Standing, Monolayered Organometallic Sheets at the Air/Water Interface [J].

Bauer, Thomas ;

Zheng, Zhikun ;

Renn, Alois ;

Enning, Raoul ;

Stemmer, Andreas ;

Sakamoto, Junji ;

Schlueter, A. Dieter .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (34) :7879-7884

[9] UNIMOLECULAR PHOTOCHEMISTRY OF ANTHRACENES [J].

BECKER, HD .

CHEMICAL REVIEWS, 1993, 93 (01) :145-172

[10] Tuning delamination of layered covalent organic frameworks through structural design [J].

Berlanga, Isadora ;

Mas-Balleste, Ruben ;

Zamora, Felix .

CHEMICAL COMMUNICATIONS, 2012, 48 (64) :7976-7978

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