Iridium-Catalyzed Annulation of Salicylimines with 1,3-Dienes

被引：35

作者：

Ebe, Yusuke ^{[1
]}

Nishimura, Takahiro ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 26期

关键词：

BOND-FORMING HYDROGENATION; CHIRAL DIENE LIGANDS; N-SULFONYL KETIMINES; ASYMMETRIC-SYNTHESIS; ANTIHYPERTENSIVE ACTIVITY; AROMATIC KETIMINES; IMINE VINYLATION; ALLYLIC AMINES; HOMOALLYLATION; ALDEHYDES;

D O I：

10.1021/ja504990a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Iridium-catalyzed annulation of salicylimines with 1,3-dienes gave high yields of the corresponding 4-aminochromanes with high stereoselectivity. The use of a chiral diene ligand enabled the asymmetric reaction to give 4-aminochromanes with high enantioselectivity.

引用

页码：9284 / 9287

页数：4

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