Spontaneous Growth of CaBi4Ti4O15Piezoelectric Crystal Using Mixed Flux Agents

被引：6

作者：

Fan, Mengdi ^{[1
,2
]}

Wu, Guangda ^{[1
,2
]}

Yu, Fapeng ^{[1
,2
]}

Li, Lili ^{[1
,2
]}

Li, Yanlu ^{[1
,2
]}

Cheng, Xiufeng ^{[1
,2
]}

Zhao, Xian ^{[1
,2
,3
]}

机构：

[1] Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China

[2] Shandong Univ, Inst Crystal Mat, Jinan 250100, Peoples R China

[3] Shandong Univ, Ctr Opt Res & Engn, Qingdao 266237, Peoples R China

来源：

CRYSTALS | 2020年 / 10卷 / 08期

基金：

中国国家自然科学基金;

关键词：

CaBi4Ti4O15; single crystal growth; flux method; dipole moments; HIGH-TEMPERATURE SOLUTION; TOTAL-ENERGY CALCULATIONS; SUBSTITUTION; DISTORTION; CERAMICS;

D O I：

10.3390/cryst10080698

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The bismuth layer-structured ferroelectrics (BLSFs) materials have potential for high-temperature piezoelectric applications. Among these piezoelectric materials, the CaBi4Ti4O15(CBT) piezoelectric ceramic with a high decomposition temperature of about 1250 degrees C attracts a lot of attention. Achieving a CBT single crystal is a significant way to improve its piezoelectric properties. For this purpose, the flux system for growing CBT crystal was explored in this study. The optimum flux composition ratio was found to be PbO:B2O3:CBT = 3:3:1 in mol%, where the PbO-B(2)O(3)mixtures were used as a flux system. Millimeter size flake-shaped CBT crystals were obtained using the spontaneous growth process for the first time. The relationship between the crystal structure and flake growth habit was analyzed. In addition, the bandgap was evaluated by the combination of transmittance spectrum and first-principle calculations. Besides, the piezoelectric property was predicted from the perspective of polyhedral distortion, which indicated the potential of CBT crystal for piezoelectric applications.

引用

页码：1 / 10

页数：10

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