Metal-free C-S coupling of thiols and disulfides

被引：53

作者：

Pramanik, Milan ^{[1
]}

Choudhuri, Khokan ^{[1
]}

Mal, Prasenjit ^{[1
]}

机构：

[1] HBNI, Natl Inst Sci Educ & Res NISER, Sch Chem Sci, PO Bhimpur Padanpur,Via Jatni, Bhubaneswar 752050, Odisha, India

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2020年 / 18卷 / 43期

关键词：

REGIOSELECTIVE SULFENYLATION; BOND FORMATION; EFFICIENT ACCESS; FACILE ACCESS; KETO ACIDS; THIOPHENOLS; THIOLATION; OXIDATION; IMIDAZOHETEROCYCLES; ALKENES;

D O I：

10.1039/d0ob01741h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In organic synthesis, transition-metal and photoredox-catalysis-based reaction systems are emerging trends for the construction of C-S bonds. Many review articles have recently appeared in this field; however, we present herein an overview of metal-free C-S coupling reactions using thiols or disulfides as sulfur surrogates. The oxidants we have considered include peroxides, tert-butyl nitrite (TBN), DDQ, iodine reagents, and molecular oxygen. In addition, selective electrochemical oxidative transformations are also covered with mechanistic details.

引用

页码：8771 / 8792

页数：22

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