Novel Benzo-15-crown-5/C60 Dyads with Different Chains: Synthesis and Complexation Properties

被引：1

作者：

Hong, Biqiong ^{[1
,2
]}

Yang, Fafu ^{[1
,3
]}

Ye, Jinqi ^{[1
]}

Guo, Hongyu ^{[1
]}

Yan, Xiaoyun ^{[4
]}

机构：

[1] Fujian Normal Univ, Coll Chem & Chem Engn, Fuzhou 350007, Peoples R China

[2] Command Acad Fuzhou, Chinese Peoples Armed Police Force, Fuzhou 350002, Peoples R China

[3] Fujian Key Lab Polymer Mat, Fuzhou 350007, Peoples R China

[4] Xiamen Univ, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China

来源：

LETTERS IN ORGANIC CHEMISTRY | 2014年 / 11卷 / 01期

基金：

中国国家自然科学基金;

关键词：

C-60; benzo-15-crown-5; chain; synthesis; complexation; FULLERENE; COLUMNS; BEARING;

D O I：

10.2174/157017861101140113155347

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Using benzo-15-crown-5 derivatives as starting materials, two novel benzo-15-crown-5/C-60 dyads with different linking chains were designed and synthesized in good yields by 1,3-dipolar cycloaddition of azomethine ylide generated in situ from aldehyde and sarcosine tied to C-60. It was found that their UV-Vis absorption spectra could be regulated hypsochromically by metal ions complexation. The long and soft linking chain was favorable for cooperate interaction of crown ether unit and C-60 unit.

引用

页码：2 / 5

页数：4

共 50 条

[31] A new synthesis of trifluoromethanethiolates - characterization and properties of tetramethylammonium, cesium and di(benzo-15-crown-5)cesium trifluoromethanethiolates
Tyrra, W
Naumann, D
Hoge, B
Yagupolskii, YL
JOURNAL OF FLUORINE CHEMISTRY, 2003, 119 (01) : 101 - 107
[32] Synthesis, Crystal Structure, and Vibrational Spectra of an Azomethine Derivativeof Benzo-15-crown-5, N-(4′-Benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldimine
L. Kh. Minacheva
I. S. Ivanova
A. V. Dorokhov
A. V. Bicherov
A. S. Burlov
A. D. Garnovskii
V. S. Sergienko
A. Yu. Tsivadze
Doklady Chemistry, 2004, 398 : 179 - 184
[33] The novel benzo-15-crown-5 with palladium(II) complex:: [Na(B15C5)]2[Pd(SCN)4]
Zhu, LY
Dou, JM
Liu, Y
Sun, DZ
Zheng, PJ
Du, CX
Zhu, Y
CHINESE CHEMICAL LETTERS, 2000, 11 (09) : 835 - 838
[34] Molecular design of crown ethers. 21. Synthesis of novel double-armed benzo-15-crown-5 lariats and their complexation thermodynamics with light lanthanoid nitrates in acetonitrile
Liu, Y
Zhang, HY
Bai, XP
Wada, T
Inoue, Y
JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (21): : 7105 - 7109
[35] Synthesis, crystal structure, and vibrational spectra of an azomethine derivativeof benzo-15-crown-5, N-(4′-benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldimine
Minacheva, LK
Ivanova, IS
Dorokhov, AV
Bicherov, AV
Burlov, AS
Garnovskii, AD
Sergienko, VS
Tsivadze, AY
DOKLADY CHEMISTRY, 2004, 398 (1-3) : 179 - 183
[36] Synthesis, characterization, and antimicrobial activities of novel double-armed benzo-15-crown-5 and their sodium and potassium complexes
Sener Cemaloglu, Oznur
Ogutcu, Hatice
Hayvali, Zeliha
JOURNAL OF CHEMICAL RESEARCH, 2021, 45 (1-2) : 116 - 124
[37] Synthesis and Thermal Behaviour of Lanthanide Complexes of 4′-[(Cholesteryloxy)Carbonyl]-Benzo-15-Crown-5
Koen Binnemans
Bilgi Gndogan
JournalofRareEarths, 2002, (04) : 249 - 255
[38] SYNTHESIS　OF　BENZO－15－CROWN－5　PHENOL－FORMALDEHYDE　RESIN　FOR　LITHIUM　ISOTOPE　SEPARATION
YOU Heng SHI
Qun YAN
Duo Yuan WANG
Xiao Zhi ZHANG
Zhong Guo DENG
Hui Bao LU (Institute of Photographic Chemistry
ChineseChemicalLetters, 1996, (03) : 289 - 292
[39] Synthesis of some novel quinone diimine derivatives of benzo-15-crown-5 for application in Hg2+ recognition
Jagadale, S. D.
Sawant, A. D.
Patil, P. P.
Patil, D. R.
Mulik, A. G.
Chandam, D. R.
Sankpal, S. A.
Deshmukh, M. B.
LUMINESCENCE, 2014, 29 (06) : 586 - 590
[40] Synthesis and spectroscopic characterization of new Schiff bases containing the benzo-15-crown-5 moiety
Hayvali, Z
Hayvali, M
Dal, H
MOLECULES, 2004, 9 (10) : 860 - 866

← 1 2 3 4 5 →