Novel Benzo-15-crown-5/C60 Dyads with Different Chains: Synthesis and Complexation Properties

被引：1
|
作者：
Hong, Biqiong [1 ,2 ]
Yang, Fafu [1 ,3 ]
Ye, Jinqi [1 ]
Guo, Hongyu [1 ]
Yan, Xiaoyun [4 ]
机构：
[1] Fujian Normal Univ, Coll Chem & Chem Engn, Fuzhou 350007, Peoples R China
[2] Command Acad Fuzhou, Chinese Peoples Armed Police Force, Fuzhou 350002, Peoples R China
[3] Fujian Key Lab Polymer Mat, Fuzhou 350007, Peoples R China
[4] Xiamen Univ, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China
来源：
LETTERS IN ORGANIC CHEMISTRY | 2014年 / 11卷 / 01期
基金：
中国国家自然科学基金;
关键词：
C-60; benzo-15-crown-5; chain; synthesis; complexation; FULLERENE; COLUMNS; BEARING;
D O I：
10.2174/157017861101140113155347
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Using benzo-15-crown-5 derivatives as starting materials, two novel benzo-15-crown-5/C-60 dyads with different linking chains were designed and synthesized in good yields by 1,3-dipolar cycloaddition of azomethine ylide generated in situ from aldehyde and sarcosine tied to C-60. It was found that their UV-Vis absorption spectra could be regulated hypsochromically by metal ions complexation. The long and soft linking chain was favorable for cooperate interaction of crown ether unit and C-60 unit.
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页码：2 / 5
页数：4
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