Recent Progress on the Long-Term Stability of Perovskite Solar Cells

被引:359
作者
Fu, Qingxia [1 ]
Tang, Xianglan [1 ]
Huang, Bin [1 ]
Hu, Ting [1 ,2 ]
Tan, Licheng [1 ,2 ]
Chen, Lie [1 ,2 ]
Chen, Yiwang [1 ,2 ]
机构
[1] Nanchang Univ, Coll Chem, 999 Xuefu Ave, Nanchang 330031, Jiangxi, Peoples R China
[2] Nanchang Univ, Inst Polymers, Jiangxi Prov Key Lab New Energy Chem, 999 Xuefu Ave, Nanchang 330031, Jiangxi, Peoples R China
基金
中国国家自然科学基金;
关键词
degradation; mechanisms; perovskite solar cells; stability; HOLE-TRANSPORTING MATERIAL; INORGANIC HYBRID MATERIALS; OPEN-CIRCUIT VOLTAGE; HIGH-PERFORMANCE; HIGHLY EFFICIENT; CH3NH3PBI3; PEROVSKITE; HALIDE PEROVSKITE; CONDUCTOR-FREE; THIN-FILMS; LEAD TRIHALIDE;
D O I
10.1002/advs.201700387
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
As rapid progress has been achieved in emerging thin film solar cell technology, organic-inorganic hybrid perovskite solar cells (PVSCs) have aroused many concerns with several desired properties for photovoltaic applications, including large absorption coefficients, excellent carrier mobility, long charge carrier diffusion lengths, low-cost, and unbelievable progress. Power conversion efficiencies increased from 3.8% in 2009 up to the current world record of 22.1%. However, poor long-term stability of PVSCs limits the future commercial application. Here, the degradation mechanisms for unstable perovskite materials and their corresponding solar cells are discussed. The strategies for enhancing the stability of perovskite materials and PVSCs are also summarized. This review is expected to provide helpful insights for further enhancing the stability of perovskite materials and PVSCs in this exciting field.
引用
收藏
页数:17
相关论文
共 195 条
[31]   Layer-by-Layer Growth of CH3NH3PbI3-xClx for Highly Efficient Planar Heterojunction Perovskite Solar Cells [J].
Chen, Yonghua ;
Chen, Tao ;
Dai, Liming .
ADVANCED MATERIALS, 2015, 27 (06) :1053-1059
[32]   Planar heterojunction perovskite/PC71BM solar cells with enhanced open-circuit voltage via a (2/1)-step spin-coating process [J].
Chiang, Chien-Hung ;
Tseng, Zong-Liang ;
Wu, Chun-Guey .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (38) :15897-15903
[33]   Transformation of the Excited State and Photovoltaic Efficiency of CH3NH3PbI3 Perovskite upon Controlled Exposure to Humidified Air [J].
Christians, Jeffrey A. ;
Miranda Herrera, Pierre A. ;
Kamat, Prashant V. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (04) :1530-1538
[34]   An Inorganic Hole Conductor for Organo-Lead Halide Perovskite Solar Cells. Improved Hole Conductivity with Copper Iodide [J].
Christians, Jeffrey A. ;
Fung, Raymond C. M. ;
Kamat, Prashant V. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (02) :758-764
[35]   MAPbl3-x Clx Mixed Halide Perovskite for Hybrid Solar Cells: The Role of Chloride as Dopant on the Transport and Structural Properties [J].
Colella, Silvia ;
Mosconi, Edoardo ;
Fedeli, Paolo ;
Listorti, Andrea ;
Gazza, Francesco ;
Orlandi, Fabio ;
Ferro, Patrizia ;
Besagni, Tullo ;
Rizzo, Aurora ;
Calestani, Gianluca ;
Gigli, Giuseppe ;
De Angelis, Filippo ;
Mosca, Roberto .
CHEMISTRY OF MATERIALS, 2013, 25 (22) :4613-4618
[36]   Perovskite-Based Hybrid Solar Cells Exceeding 10% Efficiency with High Reproducibility Using a Thin Film Sandwich Approach [J].
Conings, Bert ;
Baeten, Linny ;
De Dobbelaere, Christopher ;
D'Haen, Jan ;
Manca, Jean ;
Boyen, Hans-Gerd .
ADVANCED MATERIALS, 2014, 26 (13) :2041-2046
[37]   Excitons versus free charges in organo-lead tri-halide perovskites [J].
D'Innocenzo, Valerio ;
Grancini, Giulia ;
Alcocer, Marcelo J. P. ;
Kandada, Ajay Ram Srimath ;
Stranks, Samuel D. ;
Lee, Michael M. ;
Lanzani, Guglielmo ;
Snaith, Henry J. ;
Petrozza, Annamaria .
NATURE COMMUNICATIONS, 2014, 5
[38]   Cesium power: low Cs+ levels impart stability to perovskite solar cells [J].
Deepa, Melepurath ;
Salado, Manuel ;
Calio, Laura ;
Kazim, Samrana ;
Shivaprasad, S. M. ;
Ahmad, Shahzada .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2017, 19 (05) :4069-4077
[39]   Scalable fabrication of efficient organolead trihalide perovskite solar cells with doctor-bladed active layers [J].
Deng, Yehao ;
Peng, Edwin ;
Shao, Yuchuan ;
Xiao, Zhengguo ;
Dong, Qingfeng ;
Huang, Jinsong .
ENERGY & ENVIRONMENTAL SCIENCE, 2015, 8 (05) :1544-1550
[40]   Hole-Transporting Materials for Perovskite-Sensitized Solar Cells [J].
Dhingra, Pankul ;
Singh, Pallavi ;
Rana, Prem Jyoti Singh ;
Garg, Akshat ;
Kar, Prasenjit .
ENERGY TECHNOLOGY, 2016, 4 (08) :891-938