Reaction of 3-carene with some nitrating agents

被引:2
|
作者
Bakhvalov, OV [1 ]
Bagryanskaya, IY [1 ]
Gatilov, YV [1 ]
Korchagina, DV [1 ]
Barkhash, VA [1 ]
机构
[1] Russian Acad Sci, Siberian Div, Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia
关键词
Nitrate; Dioxide; Organic Chemistry; Nitric Acid; Dinitrogen;
D O I
10.1023/A:1016590904826
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
From the reaction products obtained by treating 3-carene with dinitrogen tetroxide a crystalline compound N-[(1R,6R)-3-methyl-6-(1-methyl-1-nitroxyethyl)cyclohex-3-enyl]-N'-{1S,6S)-4- methyl-6(1-methyl-1-nitroxyethyl)cyclo-hex-3-enyl]-E-diazene-N,N'-dioxide was isolated. Mainly nitrate of alpha-terpineol formed in reaction of 3-carene with 70% nitric acid.
引用
收藏
页码:507 / 510
页数:4
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