U- to Z-shape isomerization in a Pt2Ag2 framework containing pyridyl-NHC ligands

被引：12
作者：
Horiuchi, Shinnosuke [1 ]
Moon, Sangjoon [1 ]
Sakuda, Eri [1 ]
Ito, Akitaka [2 ]
Arikawa, Yasuhiro [1 ]
Umakoshi, Keisuke [1 ]
机构：
[1] Nagasaki Univ, Grad Sch Engn, Div Chem & Mat Sci, 1-14 Bunkyo Machi, Nagasaki 8528521, Japan
[2] Kochi Univ Technol, Sch Environm Sci & Engn, Grad Sch Engn, 185 Miyanokuchi, Kami, Kochi 7828502, Japan
来源：
DALTON TRANSACTIONS | 2018年 / 47卷 / 21期
关键词：
N-HETEROCYCLIC CARBENE; METAL-METAL INTERACTIONS; HETEROPOLYNUCLEAR COMPLEXES; PLATINUM(II) COMPLEXES; LUMINESCENT PROPERTIES; BIMETALLIC CATALYSIS; EXCITED-STATE; TRANSITION; 3,5-DIMETHYLPYRAZOLATE; PHOTOLUMINESCENCE;
D O I：
10.1039/c8dt01047a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Synthesis and isomerization of a heteropolynuclear Pt2Ag2 complex containing pyridyl N-heterocyclic carbene (NHC) ligands are reported. The Pt2Ag2 complex could take two geometrical isomers possessing a twisted U-shaped structure and a Z-shaped structure. The rate of the isomerization reaction depended on the concentration of the solution, implying that the reaction took place through an intermolecular process.
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收藏
页码：7113 / 7117
页数：5
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