Iridium-Catalyzed Hydrogenation and Dehydrogenation of N-Heterocycles in Water under Mild Conditions

被引：62

作者：

Wang, Shengdong ^{[1
]}

Huang, Haiyun ^{[1
]}

Bruneau, Christian ^{[1
]}

Fischmeister, Cedric ^{[1
]}

机构：

[1] Univ Rennes, CNRS, ISCR, UMR 6226, F-35000 Rennes, France

来源：

CHEMSUSCHEM | 2019年 / 12卷 / 11期

关键词：

dehydrogenation; homogeneous catalysis; hydrogenation; iridium; quinolines; NITROGEN-HETEROCYCLES; REVERSIBLE DEHYDROGENATION; PALLADIUM NANOPARTICLES; ACCEPTORLESS DEHYDROGENATION; SELECTIVE HYDROGENATION; COVALENT BONDS; EFFICIENT; QUINOLINES; COMPLEXES; RUTHENIUM;

D O I：

10.1002/cssc.201900626

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient catalytic method is presented for the hydrogenation of N-heterocycles. The iridium-based catalyst operates under mild conditions in water without any co-catalyst or stoichiometric additives. The catalyst also promotes the reverse reaction of dehydrogenation of N-heterocycles, hence displaying appropriate characteristics for a future hydrogen economy based on liquid organic hydrogen carriers (LOHCs)

引用

页码：2350 / 2354

页数：5

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