Conversion of Chicken Feather Waste to N-Doped Carbon Nanotubes for the Catalytic Reduction of 4-Nitrophenol

被引:117
作者
Gao, Lei [1 ,2 ]
Li, Ran [1 ,2 ]
Sui, Xuelin [3 ,4 ]
Li, Ren [1 ,2 ]
Chen, Changle [3 ,4 ]
Chen, Qianwang [1 ,2 ]
机构
[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China
[2] Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei 230026, Peoples R China
[3] Univ Sci & Technol China, CAS Key Lab Soft Matter Chem, Hefei 230026, Peoples R China
[4] Univ Sci & Technol China, Dept Polymer Sci & Engn, Hefei 230026, Peoples R China
基金
中国国家自然科学基金;
关键词
FILMS; MICROSPHERES; GRAPHENE; KERATIN;
D O I
10.1021/es5021839
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Poultry feather is renewable, inexpensive and abundantly available. It holds great business potentials if poultry feather can be converted into valuable functional materials. Herein, we describe a strategy for the catalytic conversion of chicken feather waste to Ni3S2-carbon coaxial nanofibers (Ni3S2@C) which can be further converted to nitrogen doped carbon nanotubes (N-CNTs). Both Ni3S2@C and N-CNTs exhibit high catalytic activity and good reusability in the reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) by NaBH4 with a first-order rate constant (k) of 0.9 x 10(-3) s(-1) and 2.1 x 10(-3) s(-1), respectively. The catalytic activity of N-CNTs is better than that of N-doped graphene and comparable to commonly used noble metal catalysts. The N content in N-CNTs reaches as high as 6.43%, which is responsible for the excellent catalytic performance. This strategy provides an efficient and low-cost method for the comprehensive utilization of chicken feathers. Moreover, this study provides a new direction for the application of N-CNTs.
引用
收藏
页码:10191 / 10197
页数:7
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