Accessing stable zirconium carboxy-aminophosphonate nanosheets as support for highly active Pd nanoparticles

被引:42
作者
Costantino, Ferdinando [1 ]
Vivani, Riccardo [2 ]
Bastianini, Maria [1 ]
Ortolani, Luca [3 ]
Piermatti, Oriana [1 ]
Nocchetti, Morena [2 ]
Vaccaro, Luigi [1 ]
机构
[1] Univ Perugia, CEMIN, Dipartimento Chim Biol & Biotecnol, I-06123 Perugia, Italy
[2] Univ Perugia, Dipartimento Sci Farmaceut, I-06123 Perugia, Italy
[3] CNR IMM Bologna, I-40129 Bologna, Italy
关键词
SUZUKI-MIYAURA; PALLADIUM NANOPARTICLES; COUPLING REACTIONS; EFFICIENT; CATALYST; PHOSPHONATE; EXFOLIATION; DENDRIMERS; AU;
D O I
10.1039/c5cc06292f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Thin nanosheets from a layered zirconiumphosphate- carboxy-phosphonate is reported here. Small Pd nanoparticles have been supported on these nanosheets by an efficient method. The resulting Pd-catalyst was fully characterized and tested in the Suzuki-Miyaura coupling. The catalytic system proved its efficiency as it was reused for several cycles and showed low Pd leaching.
引用
收藏
页码:15990 / 15993
页数:4
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