Coefficient of thermal expansion of carbon nanotubes measured by Raman spectroscopy

被引：108

作者：

Deng, Libo ^{[1
,2
]}

Young, Robert J. ^{[2
]}

Kinloch, Ian A. ^{[2
]}

Sun, Rong ^{[1
]}

Zhang, Guoping ^{[1
]}

Noe, Laure ^{[3
]}

Monthioux, Marc ^{[3
]}

机构：

[1] Chinese Acad Sci, Shenzhen Inst Adv Technol, Shenzhen 518055, Peoples R China

[2] Univ Manchester, Sch Mat, Ctr Mat Sci, Manchester M13 9PL, Lancs, England

[3] CNRS, CEMES, UPR 8011, Toulouse, France

来源：

APPLIED PHYSICS LETTERS | 2014年 / 104卷 / 05期

基金：

英国工程与自然科学研究理事会; 中国国家自然科学基金;

关键词：

STRESS TRANSFER; COMPOSITES; TEMPERATURE; NANOCOMPOSITES; DEFORMATION;

D O I：

10.1063/1.4864056

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

The coefficient of thermal expansion (CTE) of peapod-derived double-walled carbon nanotubes and their host empty single-walled carbon nanotubes (SWCNTs) was determined using Raman spectroscopy. This was performed by measuring the dependence of Raman band frequency of the nanotubes in epoxy resin matrix composites and considering the effects of both the strain and temperature on the Raman bands. Both types of nanotubes show positive thermal expansion at room temperature of around +2 x 10(-5) K-1, and the CTE of the SWCNTs was unaffected by the introduction of the inner wall nanotubes. It was also demonstrated that the temperature-induced Raman band shifts can be used to determine both the CTE and glass transition temperature of the matrix polymers. (C) 2014 AIP Publishing LLC.

引用

页数：4

共 31 条

[1] Structural transformation from single-wall to double-wall carbon nanotube bundles [J].

Abe, M ;

Kataura, H ;

Kira, H ;

Kodama, T ;

Suzuki, S ;

Achiba, Y ;

Kato, K ;

Takata, M ;

Fujiwara, A ;

Matsuda, K ;

Maniwa, Y .

PHYSICAL REVIEW B, 2003, 68 (04)

[2] Controlled laser heating of carbon nanotubes [J].

Bassil, A ;

Puech, P ;

Tubery, L ;

Bacsa, W ;

Flahaut, E .

APPLIED PHYSICS LETTERS, 2006, 88 (17)

[3] Raman Measurements of Thermal Transport in Suspended Monolayer Graphene of Variable Sizes in Vacuum and Gaseous Environments [J].

Chen, Shanshan ;

Moore, Arden L. ;

Cai, Weiwei ;

Suk, Ji Won ;

An, Jinho ;

Mishra, Columbia ;

Amos, Charles ;

Magnuson, Carl W. ;

Kang, Junyong ;

Shi, Li ;

Ruoff, Rodney S. .

ACS NANO, 2011, 5 (01) :321-328

[4] Investigation into the deformation of carbon nanotubes and their composites through the use of Raman spectroscopy [J].

Cooper, CA ;

Young, RJ ;

Halsall, M .

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2001, 32 (3-4) :401-411

[5] Temperature dependence of the optical transition energies of carbon nanotubes:: The role of electron-phonon coupling and thermal expansion [J].

Cronin, SB ;

Yin, Y ;

Walsh, A ;

Capaz, RB ;

Stolyarov, A ;

Tangney, P ;

Cohen, ML ;

Louie, SG ;

Swan, AK ;

Ünlü, MS ;

Goldberg, BB ;

Tinkham, M .

PHYSICAL REVIEW LETTERS, 2006, 96 (12)

[6] The Effect of Stress Transfer Within Double-Walled Carbon Nanotubes Upon Their Ability to Reinforce Composites [J].

Cui, Shuang ;

Kinloch, Ian A. ;

Young, Robert J. ;

Noe, Laure ;

Monthioux, Marc .

ADVANCED MATERIALS, 2009, 21 (35) :3591-+

[7] The Effective Young's Modulus of Carbon Nanotubes in Composites [J].

Deng, Libo ;

Eichhorn, Stephen J. ;

Kao, Chih-Chuan ;

Young, Robert J. .

ACS APPLIED MATERIALS & INTERFACES, 2011, 3 (02) :433-440

[8] Characterization of the adhesion of single-walled carbon nanotubes in poly (p-phenylene terephthalamide) composite fibres [J].

Deng, Libo ;

Young, Robert J. ;

van der Zwaag, Sybrand ;

Picken, Steven .

POLYMER, 2010, 51 (09) :2033-2039

[9] Formation mechanism of peapod-derived double-walled carbon nanotubes [J].

Ding, Feng ;

Xu, Ziwei ;

Yakobson, Boris I. ;

Young, Robert J. ;

Kinloch, Ian A. ;

Cui, Shuang ;

Deng, Libo ;

Puech, Pascal ;

Monthioux, Marc .

PHYSICAL REVIEW B, 2010, 82 (04)

[10] Perspectives on Carbon Nanotubes and Graphene Raman Spectroscopy [J].

Dresselhaus, Mildred S. ;

Jorio, Ado ;

Hofmann, Mario ;

Dresselhaus, Gene ;

Saito, Riichiro .

NANO LETTERS, 2010, 10 (03) :751-758

← 1 2 3 4 →